In this study, a novel analytical method was developed for the determination of trace level bisphenol A (BPA) in bottled water and wastewater samples. Switchable solvent-based liquid phase microextraction (SSLPME) was combined with quadrupole isotope dilution (ID⁴) to improve the accuracy/precision and lower the detection limit. In the first step of this study, double isotope dilution (ID²), triple isotope dilution (ID³), quadrupole isotope dilution (ID⁴), standard addition-double isotope dilution (SA-ID²) and standard addition-triple isotope dilution (SA-ID³) were applied for the determination of BPA to check their effectiveness in terms of accuracy and precision. ID⁴ was selected as the best strategy to quantify the analyte. In order to improve the detection power, a microextraction strategy was adopted for the system and the developed combination called SSLPME-ID⁴-GC-MS was successfully applied for the trace quantification of BPA. Under the optimum conditions, percent recovery results were calculated as 99.4 ± 0.7% and 99.9 ± 0.8% for bottled water and wastewater samples spiked with BPA at 223.8 and 169.9 ng g⁻¹, respectively.