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Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis
Arimasa Matsumoto,Hirokazu Ozawa,Ayako Inumaru,Kenso Soai
New Journal of Chemistry Pub Date : 07/16/2015 00:00:00 , DOI:10.1039/C5NJ01459J
Abstract

Retgersite, nickel sulfate hexahydrate, forms a chiral crystal with space group P41212 or P43212. A chiral crystal of nickel sulfate hexahydrate was found to act as a chiral initiator of asymmetric autocatalysis, affording highly enantiomerically enriched pyrimidyl alkanols with the corresponding absolute configurations.

Graphical abstract: Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis
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