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BiOBr photocatalyzed decarboxylation of glutamic acid: reaction rates, intermediates and mechanism†
Yue Li
RSC Advances Pub Date : 06/19/2015 00:00:00 , DOI:10.1039/C5RA09528J
Abstract

The degradation of glutamic acid by BiOBr under both UV and visible irradiation was investigated and compared with degradation by TiO2/UV. Analysis of the reaction rates and the distribution of intermediates was used to show that both BiOBr systems, unlike the TiO2 system, catalyze direct substrate oxidation by valance band holes.

Graphical abstract: BiOBr photocatalyzed decarboxylation of glutamic acid: reaction rates, intermediates and mechanism
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