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Bio-inspired polyenecyclization: aziridinyl polyenecyclization catalyzed by InBr3†
Yu-Jun Zhao,Li-Jun Serena Tan,Bin Li,Si-Min Li,Teck-Peng Loh
Chemical Communications Pub Date : 05/18/2009 00:00:00 , DOI:10.1039/B903696B
Abstract

This communication describes a highly efficient aziridinyl polyolefin cyclization catalyzed by InBr3 to synthesize chiral terpenoid bearing a 3-amino group in the A ring; both good yields and excellent asymmetric induction were achieved.

Graphical abstract: Bio-inspired polyenecyclization: aziridinyl polyenecyclization catalyzed by InBr3
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