[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework
K. Barthelet,D. Riou,G. Férey
Chemical Communications Pub Date : 06/11/2002 00:00:00 , DOI:10.1039/B202749F
Abstract
[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (denoted MIL-59) presents a three-dimensional framework built up from octahedral vanadium trimers joined via the isophthalate anionic linkers to delimit cages where water molecules and chlorine anions are occluded; the frustrated magnetic behaviour of MIL-59 is discussed.
![Graphical abstract: [VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework](http://hg.y866.cn/compound/lib/scimg/usr/1/B202749F.jpg)
