Carbon nanotube-supported Au–Pd alloy with cooperative effect of metal nanoparticles and organic ketone/quinone groups as a highly efficient catalyst for aerobic oxidation of amines†,10.1039/C6CC01490A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Carbon nanotube-supported Au–Pd alloy with cooperative effect of metal nanoparticles and organic ketone/quinone groups as a highly efficient catalyst for aerobic oxidation of amines†

Weiping Deng,Jiashu Chen,Jincan Kang,Qinghong Zhang,Ye Wang

Chemical Communications Pub Date : 04/26/2016 00:00:00 , DOI:10.1039/C6CC01490A

Abstract

Functionalised carbon nanotube (CNT)-supported Au–Pd alloy nanoparticles were highly efficient catalysts for the aerobic oxidation of amines. We achieved the highest turnover frequencies (>1000 h⁻¹) for the oxidative homocoupling of benzylamine and the oxidative dehydrogenation of dibenzylamine. We discovered a cooperative effect between Au–Pd nanoparticles and ketone/quinone groups on CNTs.