Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect†,10.1039/D0CC05185C

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Biomimetic systems involving sequential redox reactions in glycolysis – the sulfur effect†

Narihito Ogawa,Sei Furukawa,Yuya Kosugi,Takayuki Takazawa,Nobuhiro Kanomata

Chemical Communications Pub Date : 09/25/2020 00:00:00 , DOI:10.1039/D0CC05185C

Abstract

Magnesium hemithioacetates were used as model cysteine compounds to mimic natural hemithioacetals, and their biomimetic oxidation reactions using a model NAD⁺ compound were investigated. Cyclic hemithioacetate was found to be the best substrate for the reaction with the model NAD⁺ compound, which gave the corresponding NADH analog in excellent yield.