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Catalytic upgrading of lactic acid to fuels and chemicals by dehydration/hydrogenation and C–C coupling reactions†
Juan Carlos Serrano-Ruiz,James A. Dumesic
Green Chemistry Pub Date : 06/03/2009 00:00:00 , DOI:10.1039/B906869D
Abstract

Aqueous solutions of lactic acid can be catalytically processed over Pt(0.1%)/Nb2O5 into a spontaneously-separating organic layer that can serve as source of valuable chemicals (propanoic acid and C4–C7 ketones) and/or can be used to produce high energy-density liquid fuels (C4–C7 alcohols). The niobia support plays a key role in the synthesis by catalyzing dehydration and C–C coupling reactions.

Graphical abstract: Catalytic upgrading of lactic acid to fuels and chemicals by dehydration/hydrogenation and C–C coupling reactions
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