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Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)†
De-Liang Long,Jamie M. Cameron,Haralampos N. Miras,Chullikkattil P. Pradeep,Lin Xu,Leroy Cronin
Dalton Transactions Pub Date : 05/04/2012 00:00:00 , DOI:10.1039/C2DT30627A
Abstract

The heteropolyvanadate cluster [(n-C4H9)4N]4[MnIVV12O34]路2CH3CN has been isolated by cation exchange from K10[(MnIVV11O32)2]路20H2O. The structural transformation has been confirmed by X-ray single crystal structure determination and cryospray ionization mass spectrometry measurements.

Graphical abstract: Cation induced structural transformation and mass spectrometric observation of the missing dodecavanadomanganate(iv)
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