Blue phosphorescent platinum(ii) tetracarbene complexes with bis(triazoline-5-ylidene) ligands†
Yvonne Unger,Dirk Meyer,Thomas Strassner
Dalton Transactions Pub Date : 03/25/2010 00:00:00 , DOI:10.1039/B927099J
Abstract

Platinum(II) tetracarbene complexes with chelating bis(imidazoline-2-ylidene) ligands have recently shown to be an interesting class of phosphorescent emitters, although they exhibit emission wavelengths in the near-UV region with only moderate quantum yields. By changing the bis(imidazoline-2-ylidene) ligands to bis(triazoline-5-ylidene) ligands we have successfully shifted the emission wavelengths to the visible region of the spectrum. We herein report the synthesis of new bis- and tetracarbene complexes with bis(triazoline-5-ylidene) ligands, their photophysical properties and a solid state structure of a representative member of this new class of compounds.

Graphical abstract: Blue phosphorescent platinum(ii) tetracarbene complexes with bis(triazoline-5-ylidene) ligands