960化工网
Bulk assembly of organic metal halide nanotubes†
Haoran Lin,Chenkun Zhou,Yu Tian,Tiglet Besara,Jennifer Neu,Yan Zhou,James Bullock,Kirk S. Schanze,Wenmei Ming,Mao-Hua Du
Chemical Science Pub Date : 10/16/2017 00:00:00 , DOI:10.1039/C7SC03675B
Abstract

The organic metal halide hybrids welcome a new member with a one-dimensional (1D) tubular structure. Herein we report the synthesis and characterization of a single crystalline bulk assembly of organic metal halide nanotubes, (C6H13N4)3Pb2Br7. In a metal halide nanotube, six face-sharing metal halide dimers (Pb2Br95−) connect at the corners to form rings that extend in one dimension, of which the inside and outside surfaces are coated with protonated hexamethylenetetramine (HMTA) cations (C6H13N4+). This unique 1D tubular structure possesses highly localized electronic states with strong quantum confinement, resulting in the formation of self-trapped excitons that give strongly Stokes shifted broadband yellowish-white emission with a photoluminescence quantum efficiency (PLQE) of ∼7%. Having realized single crystalline bulk assemblies of two-dimensional (2D) wells, 1D wires, and now 1D tubes using organic metal halide hybrids, our work significantly advances the research on bulk assemblies of quantum-confined materials.

Graphical abstract: Bulk assembly of organic metal halide nanotubes
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