C to H effective ratio as a descriptor for co-processing light oxygenates and CH4 on Mo/H-ZSM-5†,10.1039/C4RA10661J

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

C to H effective ratio as a descriptor for co-processing light oxygenates and CH4 on Mo/H-ZSM-5†

Jeremy Bedard,Do-Young Hong,Aditya Bhan

RSC Advances Pub Date : 10/08/2014 00:00:00 , DOI:10.1039/C4RA10661J

Abstract

Co-processing of H₂O, CO₂, and light (C_1–2) oxygenates with CH₄ at 950 K over Mo/H-ZSM-5 catalysts results in complete fragmentation of the oxygenate and CO as the sole oxygen-containing product. The C/H_eff accounts for removal of O as CO and describes the net C₆H₆ and total hydrocarbon synthesis rates at varying (0.0–0.10) oxygenate and H₂ to CH₄ co-feed ratios.