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Chiral molecular conductor with an insulator–metal transition close to room temperature†‡
Jonathan I. Short,Toby J. Blundell,Sara J. Krivickas,Songjie Yang,John D. Wallis,Hiroki Akutsu,Yasuhiro Nakazawa,Lee Martin
Chemical Communications Pub Date : 07/09/2020 00:00:00 , DOI:10.1039/D0CC04094K
Abstract

Materials exhibiting both chirality and conductivity do not exist in nature and very few examples have been synthesised. We report here the synthesis of a chiral molecular metal which remains metallic down to at least 4.2 K. This material also exhibits room-temperature switching capabilities with a transition upon cooling below 10 °C.

Graphical abstract: Chiral molecular conductor with an insulator–metal transition close to room temperature
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