C–F bond formation with fluoride anions – highly selective iodofluorination of simple allenes†
Can Xue,Xinpeng Jiang,Chunling Fu,Shengming Ma
Chemical Communications Pub Date : 04/24/2013 00:00:00 , DOI:10.1039/C3CC42014K
Abstract
A highly regioselective (up to 99 : 1) iodofluorination reaction of simple allenes occurs under mild conditions with Et3N·3HF or Py·9HF to afford 2-iodoalken-3-yl fluorides.