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Chemical depolymerization of lignin involving the redistribution mechanism with phenols and repolymerization of depolymerized products†
Sepa Nanayakkara,Antonio F. Patti,Kei Saito
Green Chemistry Pub Date : 11/11/2013 00:00:00 , DOI:10.1039/C3GC41708E
Abstract

The first example of chemical depolymerization of lignin involving the redistribution mechanism with phenols in water with a copper catalyst was demonstrated. By using this new method, lignin can be depolymerized under mild conditions such as at 80 °C, atmospheric pressure. This invention is the first demonstration of the depolymerization of lignin using chemical degradation with phenols. The depolymerized oligomeric lignin can be repolymerized and form a polymer by the esterification of hydroxyl groups in the depolymerized oligomeric products with sebacoyl chloride.

Graphical abstract: Chemical depolymerization of lignin involving the redistribution mechanism with phenols and repolymerization of depolymerized products
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