A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2†,10.1039/D0CC02496A

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A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl2†

Alexander Kroll,Henning Steinert,Lennart T. Scharf,Thorsten Scherpf,Bert Mallick,Viktoria H. Gessner

Chemical Communications Pub Date : 06/15/2020 00:00:00 , DOI:10.1039/D0CC02496A

Abstract

The isolation, structural characterization and coordination chemistry of a di(amino)-substituted carbodiphosphorane (CDP) are reported. Compared to the analogue, dianionic bis(iminophosphoryl)methandiides, the CDP is a stronger C-, but much weaker N-donor which led to the isolation of solely C-coordinated metal complexes amongst an unusual monomeric trigonal-planar L·ZnCl₂ complex.