Chemiluminescence from the reaction of tin(ii) with tris(2,2′-bipyridyl)ruthenium(iii),10.1039/B918641G

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Chemiluminescence from the reaction of tin(ii) with tris(2,2′-bipyridyl)ruthenium(iii)

Michelle E. Gange,Simon C. Parratt,Philip Jones,Paul S. Francis,Neil W. Barnett

Analyst Pub Date : 10/27/2009 00:00:00 , DOI:10.1039/B918641G

Abstract

Unlike many other metal and metalloid ions, tin(II) elicits intense, analytically useful chemiluminescence upon reaction with tris(2,2′-bipyridyl)ruthenium(III) in acidic aqueous solution. This finding provides new insight into the nature of this widely used reagent and has enabled the first direct, selective determination of a metal ion with tris(2,2′-bipyridyl)ruthenium(III).