Chiral microporous Ti(salan)-based metal–organic frameworks for asymmetric sulfoxidation†
Chengfeng Zhu,Xu Chen,Zhiwei Yang,Xia Du,Yan Liu,Yong Cui
Chemical Communications Pub Date : 07/08/2013 00:00:00 , DOI:10.1039/C3CC43225D
Abstract
Chiral porous metal–metallosalan frameworks are constructed from an unsymmetrical chiral pyridinecarboxylate ligand derived from Ti(salan) and are shown to be heterogeneous catalysts for asymmetric oxidation of thioethers to sulfoxides.
