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Chiral discrimination in the intramolecular abstraction of allylic hydrogens by benzophenone triplets
Francisco Boscá,Inmaculada Andreu,Isabel M. Morera,Abdelouahid Samadi
Chemical Communications Pub Date : 06/03/2003 00:00:00 , DOI:10.1039/B303263A
Abstract

Using two diastereomeric compounds containing benzophenone and olefin units, significant chiral discrimination has been found in all the photophysical and photochemical processes involved in intramolecular hydrogen abstraction: overall quenching of benzophenone triplets, actual hydrogen abstraction step and π-quenching.

Graphical abstract: Chiral discrimination in the intramolecular abstraction of allylic hydrogens by benzophenone triplets
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