Comparison of heme and nonheme iron-based 1-aminocyclopropane-1-carboxylic acid oxidase mimics: kinetic, mechanistic and computational studies†,10.1039/C4RA08762C

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Comparison of heme and nonheme iron-based 1-aminocyclopropane-1-carboxylic acid oxidase mimics: kinetic, mechanistic and computational studies†

Dóra Lakk-Bogáth,Gábor Speier,Mihai Surducan,Radu Silaghi-Dumitrescu,A. Jalila Simaan,Bruno Faure,József Kaizer

RSC Advances Pub Date : 11/28/2014 00:00:00 , DOI:10.1039/C4RA08762C

Abstract

Kinetic, mechanistic and computational studies of the H₂O₂ oxidation of 1-aminocyclopropane-1-carboxylic acid (ACCH) to ethylene by heme, [Fe(III) (TPP)Cl] (TPP = meso-tetraphenylporphyrin), and nonheme-type iron complex, [Fe(II)(CH₃CN)(N₄Py)](ClO₄)₂ (N₄Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine), are described as biomimics of 1-aminocyclopropane-1-carboxylic acid oxidase (ACCO).