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CoCl2 catalysed decarboxylation-oxidation of mandelic acids by molecular oxygen
Isabelle Favier,Dominique Hébrault,Jean-Roger Desmurs
New Journal of Chemistry Pub Date : 10/29/2003 00:00:00 , DOI:10.1039/B307186C
Abstract

A series of mandelic acid derivatives was oxidised by molecular oxygen using cobalt(II) chloride as the catalyst. Benzaldehyde and/or benzoic acid derivatives were obtained in high selectivities, depending on the aromatic ring substitution. Different oxidation mechanisms are operating, depending on the mandelic acid substitution.

Graphical abstract: CoCl2 catalysed decarboxylation-oxidation of mandelic acids by molecular oxygen
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