A facile and high-recovery material for rare-metals based on a water-soluble polyallylamine with side-chain thiourea groups†
Daisuke Nagai,Megumi Yoshida,Takuya Kishi,Hisatoyo Morinaga,Yusuke Hara,Masanobu Mori,Satoshi Kawakami,Kenji Inoue
Chemical Communications Pub Date : 06/10/2013 00:00:00 , DOI:10.1039/C3CC43256D
Abstract

We describe a facile and high-recovery material for rare metals based on a polymer combining amino groups for water solubility and thiourea groups for metal complexation. Good solubility in aqueous metal ion solutions allows for homogeneous and efficient adsorption by the polymer, and a maximum PdII recovery amount (0.508 gPd gpolymer−1) greater than those of other polymers reported in the literature.

Graphical abstract: A facile and high-recovery material for rare-metals based on a water-soluble polyallylamine with side-chain thiourea groups