Crop production and quality safety system have the potential to nurture human health and improve environmental sustainability. Providing a growing global population with sufficient and healthy food is an immediate challenge. However, this system largely depends on the spraying of agrochemicals. Crop leaves are covered with different microstructures, exhibiting distinct hydrophilic, hydrophobic, or even superhydrophobic wetting characteristics, thus leading to various deposition difficulties of sprayed droplets. Here, the relationship between wettability and surface microstructure in different crop leaves from biological and interfacial structural perspectives is systematically demonstrated. A relational model is proposed in which complex microstructures lead to stronger leaf hydrophobicity. And adding surfactant with a faster dynamically migrating velocity and reducing droplet size can improve agrochemical precise deposition. These contribute toward highly accurate and efficient targeted applications with fewer agrochemicals use and promote sustainable models of eco-friendly agriculture systems.

Dietary proteins derived from animal sources, although containing well-balanced profiles of essential amino acids, have considerable environmental and adverse health effects associated with the intake of some animal protein-based products. Consuming foods based on animal proteins carries a higher risk of developing non-communicable diseases such as cancer, heart disease, non-alcoholic fatty liver disease (NAFLD), and inflammatory bowel disease (IBD). Moreover, dietary protein consumption is increasing due to population growth, posing a supply challenge. There is, therefore, growing interest in discovering novel alternative protein sources. In this context, microalgae have been recognized as strategic crops that can provide a sustainable source of protein. Compared to conventional high-protein crops, using microalgal biomass for protein production presents several advantages in food and feed in terms of productivity, sustainability, and nutritional value. Moreover, microalgae positively impact the environment by not exploiting land or causing water pollution. Many studies have revealed the potential of microalgae as an alternative protein source with the added value of positive effects on human health due to their anti-inflammatory, antioxidant, and anti-cancer properties. The main emphasis of this review is on the potential health-promoting applications of microalgae-based proteins, peptides, and bioactive substances for IBD and NAFLD.

Here, the structural, optical, and adsorptive behaviors of Ni0.075-xMnxAl0.025(OH)2(CO3)0.0125·yH2O (Ni-Mn/Al) layered double hydroxides (LDHs) are investigated to capture fluoride from aqueous media. The 2D mesoporous plate-like Ni-Mn/Al LDHs are successfully prepared via a co-precipitation method. The molar ratio of divalent to trivalent cations is maintained at 3:1 and the pH at 10. The X-ray diffraction (XRD) results confirm that the samples consist of pure LDH phases with a basal spacing of 7.66 to 7.72 Å, corresponding to the (003) planes at 2θ of 11.47o and the average crystallite sizes of 4.13 to 8.67 nm. The plate-like Mn-doped Ni-Al LDH consists of many superimposed nanosheets with a size of 9.99 nm. Energy-dispersive X-ray and X-ray photoelectron spectroscopies confirm the incorporation of Mn2+ into the Ni-Al LDH. UV–vis diffuse reflectance spectroscopy results indicate that incorporating Mn2+ into LDH enhances its interaction with light. The experimental data from the batch fluoride adsorption studies are subjected to kinetic models such as pseudo-first order and pseudo-second order. The kinetics of fluoride retention on Ni-Mn/Al LDH obey the pseudo-second-order model. The Temkin equation well describes the equilibrium adsorption of fluoride. The results from the thermodynamic studies also indicate that fluoride adsorption is exothermic and spontaneous.

Wastewater reuse is seen as an opportunity to support a circular economy and optimize water resources. However, the use of wastewater is limited by the need for the proper protection of health and the environment and demands a certain minimum quality of treated reclaimed water. The objective of this work is to evaluate the opportunities both for the agents in the water treatment chain (from municipalities to farmers) and for technology providers under the recently approved Regulation EU-2020/741. The new market and opportunities require new value chains, technology development, governance, risk assurance, and adapted local regulation. Bottlenecks also pose technological, environmental, institutional, economic, and social challenges. The identified needs and barriers must be properly addressed in order to accelerate the transformation of the water sector toward the circular economy. As a conclusion, Reg EU 2020/741 introduces minimum requirements for urban wastewater reuse and requires the definition of risk management and transparency. The real impact of regulation on circular-economy objectives is limited by water scarcity and crop profitability. Social acceptance is critical for success.

Lithium–sulfur batteries with high energy density still confront many challenges, such as polysulfide dissolution, the large volume change of sulfur, and fast capacity fading in long-term cycling. Herein, a naturally abundant clay material, halloysite, is introduced as a sulfur host material in the cathode of Li–S batteries. Nickel oxide nanoparticles are embedded into the halloysite nanotubes (NiO@Halloysite) by hydrothermal and calcination treatment to improve the affinity of halloysite nanotubes to polysulfides. The NiO@Halloysite composite loaded with sulfur (S/NiO@Halloysite) is employed as the cathode of Li–S batteries, which combines the physical confinements of tubular halloysite particles and good chemical adsorption ability of NiO. The S/NiO@Halloysite electrode exhibits a high discharge capacity of 1205.47 mAh g−1 at 0.1 C. In addition, it demonstrates enhanced cycling stability, retaining ≈60% of initial capacity after 450 cycles at 0.5 C. The synthesized NiO@Halloysite can provide a promising prospect and valuable insight into applying natural clay materials in Li–S batteries.

Protein–protein binding enables orderly biological self-organization and is therefore considered a miracle of nature. Protein‒protein binding is driven by electrostatic forces, hydrogen bonding, van der Waals force, and hydrophobic interactions. Among these physical forces, only hydrophobic interactions can be considered long-range intermolecular attractions between proteins due to the electrostatic shielding of surrounding water molecules. Low-entropy hydration shells around proteins drive hydrophobic attraction among them that essentially coordinate protein‒protein binding. Here, an innovative method is developed for identifying low-entropy regions of hydration shells of proteins by screening off pseudohydrophilic groups on protein surfaces and revealing that large low-entropy regions of the hydration shells typically cover the binding sites of individual proteins. According to an analysis of determined protein complex structures, shape matching between a large low-entropy hydration shell region of a protein and that of its partner at the binding sites is revealed as a universal law. Protein‒protein binding is thus found to be mainly guided by hydrophobic collapse between the shape-matched low-entropy hydration shells that is verified by bioinformatics analyses of hundreds of structures of protein complexes, which cover four test systems. A simple algorithm is proposed to accurately predict protein binding sites.

Compared to other battery technologies, metal–air batteries offer high specific capacities because the active material at the cathode side is supplied by ambient atmosphere. To secure and further extend this advantage, the development of highly active and stable bifunctional air electrodes is currently the main challenge that needs to be resolved. Herein, a highly active carbon-, cobalt-, and noble-metal-free MnO2/NiO-based bifunctional air electrode is presented for metal–air batteries in alkaline electrolytes. Notably, while electrodes without MnO2 reveal stable current densities over 100 cyclic voltammetry cycles, MnO2 containing samples show a superior initial activity and an elevated open circuit potential. Along this line, the partial substitution of MnO2 by NiO drastically increases the cycling stability of the electrode. X-ray diffractograms, scanning electron microscopy images, and energy-dispersive X-ray spectra are obtained before and after cycling to investigate structural changes of the hot-pressed electrodes. XRD results suggest that MnO2 is dissolved or transformed into an amorphous phase during cycling. Furthermore, SEM micrographs show that the porous structure of a MnO2 and NiO containing electrode is not maintained during cycling.

The development and utilization of biodegradable plastics is an effective way to overcome environmental pollution caused by the disposal of non-degradable plastics. Recently, polybutylene succinate co-butylene adipate co-ethylene succinate co-ethylene adipate, (PBEAS) a biodegradable polymer with excellent strength and elongation, was developed to replace conventional nylon-based non-degradable fishing nets. The biodegradable fishing gear developed in this way can greatly contribute to inhibiting ghost fishing that may occur at the fishing site. In addition, by collecting the products after use and disposing of them in composting conditions, the environmental problem such as the leakage of microplastics strongly can be prevented. In this study, the aerobic biodegradation of PBEAS fishing nets under composting conditions is evaluated and the resulting changes in physicochemical properties are analyzed. The PBEAS fishing gear exhibits a mineralization rate of 82% in a compost environment for 45 days. As a result of physicochemical analysis, PBEAS fibers show a representative decrease in molecular weight and mechanical properties under composting conditions. PBEAS fibers can be used as eco-friendly biodegradable fishing gear that can replace existing non-degradable nylon fibers, and in particular, fishing gear collected after use can be returned to nature through biodegradation under composting conditions.

Recent environmental policies have led academic, industrial, and governmental stakeholders to plan scenarios with a high share of renewable energy sources (RES), to ensure that future energy systems, composed mostly of RES, can remain stable, match the demand during seasonal variations and are economically feasible. This article considers different energy scenarios to obtain various options in terms of size, generation technologies, and grid configuration. The scenarios are studied in the POSYTYF project and are quantified through an optimization-based algorithm, where the test grids topologies are based on specific locations in Europe, and real data related to the availability of RES, as well as the demand. Different RES technologies are considered to meet requirements of grid integration of renewables at different horizons of time, up to 100% in the most futuristic case. The optimization algorithm is applied to three scenarios. It is shown that solar photovoltaic (PV) and wind can provide the renewable backbone, but they lack flexibility to achieve a very high share in the energy mix. Solar thermal and pumped hydro become important to cover the last range of integration, as they provide high flexibility, which is crucial for high share, but they are expensive for low share.

Solar evaporation is a facile and promising technology to efficiently utilize renewable energy for freshwater production and seawater desalination. Here, the fabrication of self-regenerating hydrogel composed of 2D-MXenes nanosheets embedded in perovskite La 0.6Sr 0.4Co 0.2Fe 0.8O3−δ (LSCF)/polyvinyl alcohol hydrogels for efficient solar-driven evaporation and seawater desalination is reported. The mixed dimensional LSCF/Ti3C2 composite features a localized surface plasmonic resonance effect in the polymeric network of polyvinyl alcohol endows excellent evaporation rates (1.98 kg m−2 h−1) under 1 k Wm−2 or one sun solar irradiation ascribed by hydrophilicity and broadband solar absorption (96%). Furthermore, the long-term performance reveals smooth mass change (13.33 kg m−2) during 8 h under one sun. The composite hydrogel prompts the dilution of concentrated brines and redissolves it back to water (1.2 g NaCl/270 min) without impeding the evaporation rate without any salt-accumulation. The present research offers a substantial opportunity for solar-driven evaporation without any salt accumulation in real-life applications.

Over recent decades, there has been a dramatic increase in the manufacture of engineered nanomaterials, which has inevitably led to their environmental release. Zinc oxide (ZnO) is among the more abundant nanomaterial manufactured due to its advantageous properties, used for piezoelectric, semiconducting, and antibacterial purposes. Plastic waste is ubiquitous and may break down or delaminate into smaller microplastics, leaving open the question of whether these small polymers may alter the fate of ZnO through adsorption within aquatic media (tap-water and seawater). Here, scanning electron microscopy analysis confirms the effective Zn nano/microstructures adsorption onto polystyrene surfaces after only 24-h incubation in the aquatic media. After pre-aging the nanomaterials for 7-days in different environmental media, nanoprobe X-ray absorption near-edge spectroscopy analysis reveals significant ZnO transformation toward Zn-sulfide and Zn-phosphate. The interaction between a commercial ZnO-based sunscreen with polystyrene and a cleanser consumer containing microbeads with ZnO nanomaterials is also studied, revealing the adsorption of transformed Zn-species in the microplastics surfaces, highlighting the environmental relevancy of this work. Understanding the structural and functional impacts of the microplastics/ZnO complexes, and how they evolve, will provide insights into their chemical nature, stability, transformations, and fate, which is key to predicting their bioreactivity in the environment.

The paradigm shift from traditional petroleum-based non-recyclable thermosets to biobased repeatedly recyclable materials is required to move toward circular bioeconomy. Here, two mechanically and chemically recyclable extended vanillin-derived epoxy thermosets are successfully fabricated by introduction of Schiff-base/imine covalent dynamic bonds. Thermoset 1 (T1) is based on linear monomer 1 (M1) with two alcohol end groups and one imine bond, while thermoset 2 (T2) is based on branched monomer 2 (M2) with three alcohol end-groups and three imine-groups. Thermosets are obtained by reaction of monomer 1 (M1) and monomer 2 (M2) with trimethylolpropane triglycidyl ether. The structure of the monomers and thermosets is confirmed by nuclear magnetic resonance and Fourier transform infrared spectroscopic techniques. Both thermosets exhibit good thermal and mechanical properties and they are stable in common organic solvents. Furthermore, they can be thermally reprocessed through compression molding with good recovery of the mechanical properties. Last but not least, the fabricated thermosets can be rapidly and completely chemically recycled to water-soluble aldehydes and amines by imine hydrolysis at room temperature in 0.1 m HCl solution. This is promising for development of future materials with multiple circularity by different routes.

The potential of seaweed to mitigate methane is real and studies with red seaweeds have found reductions in methane produced from ruminants fed red seaweeds in the region of 60–90% where the active compound responsible for this is bromoform. Other studies with brown and green seaweeds have observed reductions in methane production of between 20 and 45% in vitro and 10% in vivo. Benefits of feeding seaweeds to ruminants are seaweed specific and animal species-dependent. In some instances, positive effects on milk production and performance are observed where selected seaweeds are fed to ruminants while other studies note reductions in performance traits. A balance between reducing methane and maintaining animal health and food quality is necessary. Seaweeds are a source of essential amino acids and minerals however, and offer huge potential for use as feeds for animal health maintenance once formulations and doses are correctly prepared and administered. A negative aspect of seaweed use for animal feed currently is the cost associated with wild harvest and indeed aquaculture production and improvements must be made here if seaweed ingredients are to be used as a solution to control methane production from ruminants for continued production of animal/ruminant sourced proteins in the future. This review collates information concerning different seaweeds and how they and their constituents can reduce methane from ruminants and ensure sustainable production of ruminant proteins in an environmentally beneficial manner.

Flexible thin-film thermoelectric devices (TEDs) can generate electricity from the heat emitted by the human body, which holds great promise for use in energy supply and biomonitoring technologies. The p-type Sb2Te3 hexagon nanosheets are prepared by the hydrothermal synthesis method and compounded with Ti3C2Tx to make composite films, and the results show that the Ti3C2Tx content has a significant impact on the thermoelectric properties of the composite films. When the Ti3C2Tx content is 2 wt%, the power factor of the composite film reaches ≈59 µW m−1 K−2. Due to the outstanding electrical conductivity, high specific surface area, and excellent flexibility of Ti3C2Tx, the composite films also exhibit excellent thermoelectric and mechanical properties. Moreover, the small addition of Ti3C2Tx has a negligible effect on the phase composition of Sb2Te3 films. The TED consists of seven legs with an output voltage of 45 mV at ΔT = 30 K. The potential of highly flexible thin film TEDs for wearable energy collecting and sensing is great.

CO2 capture and storage (CCS) is an important strategy to reduce global CO2 emissions. This work presents both cutting-edge carbon storage tanker design, as well as novel reliability method making possible to extract useful information about the lifespan distribution of carbon capture systems from their recorded time history. The method outlined may be applied on more complex sustainable systems that are exposed to environmental stresses throughout the whole period of their planned service life. The latter is of paramount importance at the design stage for complex engineering systems. Novel design for CCS system is discussed and accurate numerical simulation results are used to apply suggested novel reliability methodology. Furthermore, traditional reliability approaches that deal with complex energy systems are not well suited for handling high dimensionality and cross-correlation between various system components of innovative dynamic CO2 storage subsea shuttle tanker. This study has two distinctive key features: the state of art CCS design concept, and the novel general purpose reliability method, recently developed by authors, and particularly suitable for operational safety study of complex energy systems.

To enable a future society based on sun and wind energy, transforming electricity into chemical energy in the form of fuels is crucial. This transformation can be achieved in an electrolyzer performing water splitting, where at the anode, water is oxidized to oxygen—oxygen evolution reaction (OER)—to produce protons and electrons that can be combined at the cathode to form hydrogen—hydrogen evolution reaction (HER). While hydrogen is a desired fuel, the obtained oxygen has no economic value. A techno-economically more suitable alternative is hybrid water electrolysis, where value-added oxidation reactions of abundant organic feedstocks replace the OER. However, tremendous challenges remain for the industrial-scale application of hybrid water electrolysis. Herein, these challenges, including the higher kinetic overpotentials of organic oxidation reactions compared to the OER, the small feedstock availably and product demand of these processes compared to the HER (and carbon dioxide reduction), additional purifications costs, and electrocatalytic challenges to meet the industrially required activities, selectivities, and especially long-term stabilities are critically discussed. It is anticipated that this perspective helps the academic research community to identify industrially relevant research questions concerning hybrid water electrolysis.

Transnational public–private governance initiatives (TGIs) have become key elements in global governance, especially in the governance of sustainability. Pertinent research has concentrated on why TGIs have emerged as well as on their impacts on political outcomes and questions related to their legitimacy. This instructive literature has predominantly focused on TGIs as entities in their own right. This explorative study contributes to the literature by advocating a complementary analytical perspective that pays attention to domestic-level patterns of participation in TGIs and national factors that determine which types of organizations (public, business, or civil society) participate in TGIs. It is shown for six Latin American countries (Argentina, Brazil, Chile, Colombia, Mexico, and Peru) that there exists cross-country variation in the composition patterns in 29 TGIs on sustainability, suggesting that national conditions matter for how organizations participate in them. By improving the knowledge of the national conditions, a more complete analysis of participation and the effectiveness of TGIs can be provided in global sustainability governance. In this spirit, in a last step, an agenda is developed for guiding future research on this topic.

Owing to the increasing global demand for carbon resources, pressure on finite materials, including petroleum and inorganic resources, is expected to increase in the future. Efficient utilization of waste resources has become crucial for sustainable resource acquisition for creating the next generation of industries. Rice husks, which are abundant worldwide as agricultural waste, are a rich carbon source with a high silica content and have the potential to be an effective raw material for energy-related and environmental purification materials such as battery, catalyst, and adsorbent. Converting these into valuable resources often requires separation and carbonization; however, these processes incur significant energy losses, which may offset the benefits of using biomass resources in the process steps. This review summarizes and discusses the high value of RHs, which are abundant as agricultural waste. Technologies for separating and converting RHs into valuable resources by hydrothermal carbonization are summarized based on the energy efficiency of the process.