10031-26-2 (溴化铁(III),Iron(III) Bromide)

CAS号:
10031-26-2
中文名称:
溴化铁(III)
英文名称:
Iron(III) Bromide
安全信息:
分子式:
Br3Fe
分子量:
295.556999206543

溴化铁(III)(10031-26-2)名称与标识符

名称

中文别名:
溴化铁(III);溴化铁无水;无水溴化铁;溴化铁;溴化铁(Ⅲ);三溴高铁;三溴化铁;溴化高铁;溴化铁(III) 无水,;溴化鐵;无水三溴化铁;溴化铁 5G;溴化铁(III) 无水,98+%;溴化铁(III), 试剂级;
英文别名:
iron tribromide;IRON (III) BROMIDE;iron(3+),tribromide;IRON BROMIDE;FERRIC BROMIDE;Tribromoiron(III);Iron bromide(FeBr3);Ferric(III) bromide;Iron(III) tribromide;Iron(III) bromide;Iron(III) bromide 98%;Iron(iii) bromide, 90+%;Iron bromide (FeBr3);9RDO128EH7;iron(3+) tribromide;RL00030;SY013697;Iron(Iii) Bromide, Anhydrous;IRON(III) BROMIDE ANHYDROUS;Iron(III)bromide,anhydrous,99%;EINECS 233-089-1;iron(3+);tribromide;Ferric Bromide; Iron Tribromide; Iron(III) Bromide;AKOS024256097;FERRIC BROMIDE [MI];Br3Fe;10031-26-2;UNII-9RDO128EH7;DTXSID40894107;

标识符

MDL:
MFCD00016082
InChIKey:
FEONEKOZSGPOFN-UHFFFAOYSA-K
Inchi:
1S/3BrH.Fe/h3*1H;/q;;;+3/p-3
SMILES:
[Fe](Br)(Br)Br

溴化铁(III)(10031-26-2)物化性质

实验特性

  • LogP : 2.53430
  • PSA : 0.00000
  • Merck : 14,4018
  • 水溶性 : Soluble in water, ether and alcohol.
  • 沸点 : No data available
  • 熔点 : 200 °C
  • 蒸气压 : No data available
  • 闪点 : No data available
  • 溶解度 : 溶于乙醇、乙醚
  • 颜色与性状 : 闪烁着黑色光泽的板状结晶,吸湿性极强。
  • 稳定性 : hygroscopic
  • 溶解性 : 溶于水。
  • 敏感性 : Hygroscopic
  • 密度 : 4.500

计算特性

  • 精确分子量 : 292.69000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 0
  • 同位素质量 : 292.689955
  • 重原子数量 : 4
  • 复杂度 : 0
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 4
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

溴化铁(III)(10031-26-2)安全信息

溴化铁(III)(10031-26-2)国际标准相关数据

EINECS:
233-089-1

溴化铁(III)(10031-26-2)海关数据

海关编码:
28275900

溴化铁(III)(10031-26-2)生产方法和用途

用途:
用有机合成催化剂
生产方法:
在超硬质玻璃反应管闭口端中,放入还原铁粉,开口端与真空系统连接,使经减压而蒸馏出的纯溴在铁粉上冷凝,然后在真空下熔封。将右半部分用冰冷却,溴即凝集于该部分。然后将有铁粉的左半部分加热至175~200℃,存有溴的右半部分加热至120℃,管中溴的压力可达5.65×105Pa并缓慢地进行反应,则在紧靠高温部分的外侧析出黑色板状结晶。如溴量过少或温度过高,将生成溴化亚铁的黄色结晶。 也可用无水溴化亚铁代替铁粉,将其与溴反应制备溴化铁。

溴化铁(III)(10031-26-2)相关文献

溴化铁(III)(10031-26-2) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Iron (III) bromide, anhydrous,99%    
   CAS Registry Number:       10031-26-2    
   Formula:       FeBr3    
   EINECS Number:       233-089-1    
   Chemical Family:       metal halide    
   Synonym:       Ferric bromide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10031-26-2       100%       1mg/m3 (as Fe       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes moderate to severe irritation of the eyes.    
   Skin Contact:       Causes irritation, redness, and pain to skin.    
   Inhalation:       Dust causes coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.    
   Ingestion:       Soluble iron salts may cause poisoning.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause
   Chronic Health Affects:
   pulmonary fibrosis.
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit corrosive hydrogen bromide fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   To avoid raising dust, small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate
   Spill and Leak Procedures:
   and swept up.

SECTION 7: Handling and Storage
   Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
   Handling and Storage:
   hood. Prolonged exposure to the atmosphere may lead to degradation of the product.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       reddish-black xtl.    
   Molecular Weight:       295.57    
   Melting Point:       subl. dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       Oxidizing agents, water, alcohols, active metals and halogens    
   Decomposition Products:       with moisture: hydrobromic acid and metal oxides.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A