10102-05-3 (二硝酸钯,Palladium(Ⅱ) Nitrate)

CAS号:
10102-05-3
中文名称:
二硝酸钯
英文名称:
Palladium(Ⅱ) Nitrate
安全信息:
分子式:
Pd(NO3)2
分子量:
230.43

二硝酸钯(10102-05-3)名称与标识符

名称

中文别名:
二硝酸钯;硝酸钯(II)溶液;硝酸钯,二水合物;钯(Ⅱ)硝酸盐;硝酸钯;硝酸钯(Ⅱ)溶液;硝酸钯(II);硝酸钯(II) 水合物;硝酸钯,AR;硝酸钯溶液;硝酸钯水合物;硝酸钯液体;氢氧化钯;硝酸钯,二水;硝酸亚钯;硝酸钯(II) – 硝酸 溶液;钯改进剂;无水硝酸钯;钯基体改进剂;硝酸钯 1G;硝酸钯粉末;
英文别名:
Palladium(II) nitrate dihydrate;Palladium Matrix Modifier;Palladium(II) nitrate solution;palladium dinitrate;Palladium nitrate, hydrate;Palladiumnitratedihydrate;Palladium(II) nitrate;Palladium nitrate;Palladium (II) Nitrate Hydrate;Pa Nitrate;PaladiumNitrate;PALLACIUM(II)NITRATE;PalladiuM hydroxide;Palladium nitrate di;PALLADIUM STANDARD SOLUTION;PALLADIUM(II) NITRATE 2 H2O;Palladous nitrate;Palladium(Ⅱ) Nitrate;Palladium nitrate(crystal);Palladium (II) nitrate;palladiumdinitrate;Palladium nitrate dihydrate;Palladium nitrate solution;EINECS 233-265-8;PALLADIUM(2+) ION DINITRATE;10102-05-3;palladium(2+);dinitrate;Palladium( cento) nitrate dihydrate;PALLADIUM NITRATE [MI];PALLADIUM NITRATE (PD(NO3)2);Palladium(II) nitric acid;DTXCID701022668;Q416480;Hydrogen tetranitropalladate (II);DTXSID60881413;NITRIC ACID, PALLADIUM(2+) SALT;NS00093566;Palladium(II) nitrate, Pd 39% min;AKOS015833351;Nitric acid, palladium(2+) salt (2:1);MFCD00011169;5G27LBZ05U;UNII-5G27LBZ05U;

标识符

MDL:
MFCD00011169
InChIKey:
UVCRDXRRYBAMHB-UHFFFAOYSA-N
Inchi:
1S/2NO3.Pd/c2*2-1(3)4;/q2*-1;+2
SMILES:
[N+](=O)(O)[O-].[N+](=O)(O)[O-].[Pd]

二硝酸钯(10102-05-3)物化性质

实验特性

  • LogP : 0.56820
  • PSA : 137.76000
  • Merck : 13,7060
  • 水溶性 : Soluble in water, nitric acid.
  • 沸点 : No data available
  • 熔点 : >100ºC
  • 闪点 : °C
  • 溶解度 : Soluble in dilute nitric acid.
  • 浓度 : 10.0 g/L±0.3 g/L Pd
  • 颜色与性状 : 棕黄色结晶或粉末,有潮解性。[1]
  • 溶解性 : 溶于水,溶于稀硝酸。[4]
  • 敏感性 : Hygroscopic
  • 密度 : 1.118 g/mL at 25 °C

计算特性

  • 精确分子量 : 229.87900
  • 氢键供体数量 : 2
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 229.879
  • 重原子数量 : 9
  • 复杂度 : 18.8
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 3
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 126A^2

二硝酸钯(10102-05-3)安全信息

二硝酸钯(10102-05-3)国际标准相关数据

EINECS:
233-265-8

二硝酸钯(10102-05-3)生产方法和用途

用途:
用作分析试剂,分离氯和碘,用作有机合成催化剂。
生产方法:
将金属钯粉或新制备的氢氧化钯加入浓硝酸中,水浴加热。过滤,所得滤液减压蒸馏浓缩后,放入干燥器中冷却结晶。抽滤。产品密封保存。

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二硝酸钯(10102-05-3)参考资料

Reaxys RN:
PubChem CID:

二硝酸钯(10102-05-3) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Palladium (II) nitrate hydrate(Pd approx. 40%) (99.9%-Pd)    
   CAS Registry Number:       10102-05-3    
   Formula:       Pd(NO3)2.XH2O    
   EINECS Number:       233-265-8    
   Chemical Family:       metal nitrate salts    
   Synonym:       Palladium dinitrate, Nitric acid, palladium (+2) salt    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       10102-05-3       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       Causes slight to mild irritation of the eyes    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       carbon dioxide, foam or dry powder    
   If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit irritating fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a tightly sealed container. Keep away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       brown xtl.    
   Molecular Weight:       230.72    
   Melting Point:       dec.    
   Boiling Point:       no data    
   Vapor Pressure:       not applicable    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       very soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high
   Conditions to Avoid:
   temperatures.
   Incompatibility:       reducing agents, organic matter, phosphorus and sulfur    
   Decomposition Products:       nitrogen oxides and palladium salts    

SECTION 11: Toxicological Information
   RTECS Data:       Intraperitoneal (rat); DNA inhibition: 56 umol/kg.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       Possible mutagenic effects reported in RTECS    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No data available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (CFR):       5.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       II    
   UN ID Number (CFR):       UN# 1477    
   Shipping Name (IATA):       Nitrates, Inorganic, N.O.S.    
   Hazard Class (IATA):       5.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       II    
   UN ID Number (IATA):       UN# 1477    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title Compound: See Category Code N511 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A