10262-65-4 (5-甲氧基水杨酸甲酯,2-(Bromoacetyl)-6-methoxynaphthalene)

快速询单

结构式：

5-甲氧基水杨酸甲酯MOL文件

CAS号：

10262-65-4

中文名称：

5-甲氧基水杨酸甲酯

英文名称：

2-(Bromoacetyl)-6-methoxynaphthalene

安全信息：

分子式：

C₁₃H₁₁BrO₂

分子量：

279.129243135452

5-甲氧基水杨酸甲酯(10262-65-4)名称与标识符

名称

中文别名：

2-(2-溴乙酰基)-6-甲氧基萘;2- (溴乙酰基)-6-甲氧基萘;2-(Bromoacetyl)-6-methoxynaphthalene 2-(2-溴乙酰基)-6-甲氧基萘;2-溴乙酰基-6-甲氧基萘;5-甲氧基水杨酸甲酯;2-溴-6'-甲氧基-2'-萘乙酮;布洛芬杂质20;2-(溴乙酰基)-6-甲氧基萘;

英文别名：

Ethanone, 2-bromo-1-(6-methoxy-2-naphthalenyl)-;2-(Bromoacetyl)-6-methoxynaphthalene;2-bromo-1-(6-methoxynaphthalen-2-yl)ethanone;2-(3-ETHOXYPHENOXY)ANILINE;2-bromo-1-(2-methoxynaphthalen-6-yl)ethanone;2-bromo-1-(6-methoxy-[2]naphthyl)-ethanone;2-Bromo-6'-methoxy-2'-acetonaphthone;2-Bromoacetyl-6-methoxynaphtalene;6-methoxy-2-(bromoacetyl)naphthalene;Ethanone,2-bromo-1-(6-methoxy-2-naphthalenyl);Ibuprofen Impurity 20;2-bromoacetyl-6-methoxynaphthalene;2-bromo-1-(6-methoxy-2-naphthyl)ethanone;2-Bromo-1-(6-methoxy-naphthalen-2-yl)-ethanone;2-bromo-1-(6-methoxynaphthalen-2-yl)ethan-1-one;Enamine_005243;HHHKEQGAGUAOQI-UHFFFAOYSA-N;HMS1408O07;B3496;T70026;EN300-01889;AKOS008966810;DTXSID50145415;AS-79977;SR-01000039338;IDI1_007830;SR-01000039338-1;10262-65-4;SCHEMBL571370;CS-0307555;FT-0657284;CHEMBL2268891;MFCD03964189;2-Bromo-1-(6-methoxy-2-naphthalenyl)ethanone,2'-Acetonaphthone, 2-bromo-6'-methoxy- (6CI, 7CI, 8CI),2-Bromo-1-(6-methoxy-2-naphthyl)ethanone,2-Bromo-1-(6-methoxynaphthalen-2-yl)ethan-1-one,2-Bromo-6'-methoxy-2'-acetonaphthone,2-Bromoacetyl-6-methoxynaphthalene;DTXCID7067906;SY055360;DB-058834;

标识符

MDL：

MFCD03964189

InChIKey：

HHHKEQGAGUAOQI-UHFFFAOYSA-N

Inchi：

1S/C13H11BrO2/c1-16-12-5-4-9-6-11(13(15)8-14)3-2-10(9)7-12/h2-7H,8H2,1H3

SMILES：

BrCC(C1=CC=C2C=C(C=CC2=C1)OC)=O

5-甲氧基水杨酸甲酯(10262-65-4)物化性质

实验特性

LogP : 3.42600
PSA : 26.30000
折射率 : 1.631
沸点 : 387.2 ºCat 760 mmHg
熔点 : 110.0 to 114.0 deg-C
蒸气压 : 0.0±0.9 mmHg at 25°C
闪点 : 188 ºC
密度 : 1.451

计算特性

精确分子量 : 277.99400
氢键供体数量 : 0
氢键受体数量 : 2
可旋转化学键数量 : 3
同位素质量 : 277.994
重原子数量 : 16
复杂度 : 254
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.6
互变异构体数量 : 2
表面电荷 : 0
拓扑分子极性表面积 : 26.3

5-甲氧基水杨酸甲酯(10262-65-4)安全信息

符号： GHS05
安全说明： H303+H313+H333
危险品运输编号： 3261
危害声明：H290-H314
警示性声明：P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
提示语：危险
储存条件： storage at -4℃ (1-2weeks), longer storage period at -20℃ (1-2years)
PackingGroup： II
信号词： warning
HazardClass： 8

5-甲氧基水杨酸甲酯(10262-65-4)国际标准相关数据

EINECS：

5-甲氧基水杨酸甲酯(10262-65-4)海关数据

海关编码：

2914700090

海关数据：

中国海关编码：

2914700090

概述：

2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 丙酮报明包装

Summary：

HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

5-甲氧基水杨酸甲酯(10262-65-4)推荐厂家更多厂家(16)

公司名称	手机号/电话	联系人	QQ	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
西安德而塔生物科技有限公司	18133906270 18133906270	张女士	2590956145	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
上海绩祥生物科技有限公司	13093077543	陆经理	3985448220	询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
深圳市瑞吉特生物科技有限公司	15813841136 0755-89459231	钦先生	1029374309	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单

5-甲氧基水杨酸甲酯(10262-65-4)上下游

6-甲氧基-2-乙酰萘

5-甲氧基水杨酸甲酯(10262-65-4)参考资料

Reaxys RN：

2049951

Beilstein：

8(4)1178

PubChem CID：

87561446

5-甲氧基水杨酸甲酯(10262-65-4) MSDS

基础信息

2-(Bromoacetyl)-6-methoxynaphthalene Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: 2-(Bromoacetyl)-6-methoxynaphthalene

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS
  Corrosive to metals        Category 1
  HEALTH HAZARDS
  Skin corrosion/irritation        Category 1B
    Category 1
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Danger
  Hazard statement        May be corrosive to metals
    Causes severe skin burns and eye damage
  Precautionary statements
    Keep only in original container.
  [Prevention]
    Do not breathe.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
    IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
  [Response]
    breathing.
    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    Wash contaminated clothing before reuse.
    Immediately call a POISON CENTER or doctor/physician.
    Absorb spillage to prevent material damage.
  [Storage]        Store locked up.
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  2-(Bromoacetyl)-6-methoxynaphthalene

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Component(s):        2-(Bromoacetyl)-6-methoxynaphthalene
  Percent:        >98.0%(GC)
  CAS Number:        10262-65-4
  Synonyms:        2-Bromo-6'-methoxy-2'-acetonaphthone
  Chemical Formula:        C13H11BrO2

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. Immediately call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing.Immediately call a POISON CENTER or
    doctor/physician.
  Ingestion:        Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
    induce vomiting.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (P3 filter respirator for toxic particles). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Entry to non-involved personnel should
  emergency procedures: be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a local exhaust if dust or aerosol will be
    generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.
    Use corrosive resistant equipment.
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed. Keep only in original container.
  2-(Bromoacetyl)-6-methoxynaphthalene

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator, self-contained breathing apparatus(SCBA), supplied air respirator,
    etc. Use respirators approved under appropriate government standards and follow
    local and national regulations.
    Impervious gloves.
  Hand protection:
  Eye protection:        Safety goggles. A face-shield, if the situation requires.
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
  Form:        crystal - powder
    White - Pale yellow
  Color:
  Odor:        No data available
  pH: No data available
  Melting point/freezing point:112 °C
  Boiling Point/Range:        No data available
  Flash Point:        No data available
  Explosive limits
  Lower:        No data available
    No data available
  Upper:
  Density:        No data available
    No data available
  Solubility:

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
  Reactivity:        No special reactivity has been reported.
  Incompartible materials: oxidizing agents, strong bases
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):
  2-(Bromoacetyl)-6-methoxynaphthalene

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        8: Corrosive.
  UN-No:        3261
  Proper shipping name:        Corrosive solid, acidic, organic, n.o.s.
    II
  Packing group:

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A