10421-48-4 (硝酸铁,Ferric nitrate)

结构式:
CAS号:
10421-48-4
中文名称:
硝酸铁
英文名称:
Ferric nitrate
安全信息:
分子式:
Fe[NO3]3
分子量:
241.8597
简介:
硝酸铁(化学式为Fe(NO3)3,式量241.86)。其九水合物(Mr=404.02)为无色至暗紫色的潮解性晶体,易潮解。熔点47.2℃,沸点125℃(分解),相对密度1.68(水=1),相对分子质量为241.88。易溶于水、乙醇、丙酮。
微溶于浓硝酸。由铁屑或氧化铁与浓硝酸作用而制得。用作媒染剂、铜着色剂,并供试剂、医药等用。

管制类

硝酸铁(10421-48-4)名称与标识符

名称

中文别名:
硝酸铁;液体硝酸铁;硝酸高铁;硝酸铁(III) 溶液;硝酸鐵;硝酸铁(III);AAS 铁标准品;ICP 铁标准品;原子吸收光谱铁标准溶液;铁标准液,用于原子吸收;
英文别名:
Ferric nitrate;Iron standard for AAS;EINECS 233-899-5;Iron nitrate;Iron nitrate (Fe(NO3)3);Iron trinitrate;Iron(III) nitrate,anhydrous;Nitric acid,iron(3+) salt;UN1466;UNII-N8H8402XOB;Nitricacid, iron(3+) salt (8CI,9CI);Gazhazot;Iron(III) nitrate;Iron(Ⅲ) nitrate;Eisen(III)-nitrat8;Iron(III)trinitrate;ironnitrate[fe(no3)3];nitric acid, iron salt;Iron nitrate(Fe(NO3)3);ironnitrate;irontrinitrate;

标识符

MDL:
MFCD00010999
InChIKey:
XEEYBQQBJWHFJM-UHFFFAOYSA-N
Inchi:
1S/Fe.3NO3/c;3*2-1(3)4/q+3;3*-1
SMILES:
[Fe+3].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-]

硝酸铁(10421-48-4)物化性质

实验特性

  • LogP : 0.84980
  • PSA : 206.64000
  • Merck : 13,4057
  • 沸点 : 83 oC at 760 mmHg
  • 熔点 : 47.2℃
  • 闪点 : 无意义
  • 溶解度 : H2O: soluble
  • 浓度 : 10.00 g/L Fe in nitric acid
  • 密度 : 1.05 g/mL at 20 °C

计算特性

  • 精确分子量 : 241.89800
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 241.898
  • 重原子数量 : 13
  • 复杂度 : 18.8
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 4
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 189A^2

硝酸铁(10421-48-4)国际标准相关数据

EINECS:
233-899-5

硝酸铁(10421-48-4)海关数据

海关编码:
2834299090
海关数据:

中国海关编码:

2834299090

硝酸铁(10421-48-4)相关文献

硝酸铁(10421-48-4) MSDS

基础信息

Name:Iron (III) nitrate Material Safety Data Sheet
Synonym:Ferric nitrate; Iron trinitrate; Iron nitrate
CAS:10421-48-4
Section 1 - Chemical Product ? MSDS Name:Iron (III) nitrate Material Safety Data Sheet
Synonym:Ferric nitrate; Iron trinitrate; Iron nitrate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
10421-48-4Ferric nitrate100 %233-899-5
Hazard Symbols: XI O
Risk Phrases: 36/38 8

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes and skin. Contact with combustible material may cause fire.Hygroscopic.Moisture sensitive.The toxicological properties of this material have not been fully investigated.Mutagen.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids. Get medical aid.
Skin:
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish surrounding fire.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: Not published.
Explosion Limits, Lower: Not available.
Upper: Not available.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Reduce airborne dust and prevent scattering by moistening with water. Clean up spills immediately, observing precautions in the Protective Equipment section. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid contact with skin and eyes. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Do not store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate general or local, explosion-proof ventilation to keep airborne levels to acceptable levels.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134. Always use a NIOSH-approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Appearance: light purple
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 47 deg C
Decomposition Temperature: Not available.
Solubility: Soluble in water.
Specific Gravity/Density: 1.68
Molecular Formula: N3O9Fe
Molecular Weight: 241.8617

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, combustible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizers. May discolor upon exposure to light.
Hazardous Decomposition Products:
Oxides of nitrogen, irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 10421-48-4: QU8915000 LD50/LC50:
Not available.
Carcinogenicity:
Ferric nitrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
? For further information, contact Fisher Scientific.

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
CDG/CPL
Shipping Name: FERRIC NITRATE
Hazard Class: 5.1
UN Number: 1466
Packing Group: III
IMO
No information available.
IATA
No information available.
RID/ADR
No information available.
Canadian TDG
No information available.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately with
plenty of ... (to be specified by the manufacturer).
WGK (Water Danger/Protection)
CAS# 10421-48-4: 1
Canada
CAS# 10421-48-4 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 10421-48-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10421-48-4:. OEL-DENMARK:TWA 1 mg(Fe)/m3 JANUARY 1993. OEL-FINL
AND:TWA 1 mg(Fe)/m3 JANUARY 1993. OEL-THE NETHERLANDS:TWA 1 mg(Fe)/m3
JANUARY 1993. OEL-SWITZERLAND:TWA 1 mg(Fe)/m3 JANUARY 1993. OEL-UNI
TED KINGDOM:TWA 1 mg(Fe)/m3;STEL 2 mg(Fe)/m3 JANUARY 1993. OEL IN BUL
GARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OEL IN NEW ZEALAND, SI
NGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 10421-48-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A