12132-04-6 (羰基(五甲基环茂二烯基)钼二聚合物,Pentamethylcyclopentadienylmolybdenum dicarbonyl dimer)

CAS号:
12132-04-6
中文名称:
羰基(五甲基环茂二烯基)钼二聚合物
英文名称:
Pentamethylcyclopentadienylmolybdenum dicarbonyl dimer

羰基(五甲基环茂二烯基)钼二聚合物(12132-04-6)名称与标识符

名称

中文别名:
羰基(五甲基环茂二烯基)钼二聚合物;二羰基(五甲基环茂二烯基)钼二聚合物;烟酸诺氟沙星;二羰基(五甲基环戊二烯基)钼二聚物;四羰基二[(1,2,3,4,5-eta)-1,2,3,4,5-五甲基-2,4-环戊二烯-1-基]二钼;羰基(五甲基环茂二烯基)钼二聚合物,99%;二羰基(五甲基环戊二烯基)钼二聚合物;
英文别名:
Pentamethylcyclopentadienylmolybdenum dicarbonyl dimer;Dicarbonyl(pentamethylcyclopentadienyl)molybdenum,dimer;Pentamethylcyclopentadienylmolybdenumdicarbonyldimerredxtl;Dicarbonyl(pentamethylcyclopentadienyl)molybdenum(V) dimer;DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL);DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL)-;PENTAMETHYLCYCLOPENTADIENYLMOLYBDENUM DICARBONYL DIMER 99%;Pentamethylcyclopentadienylmolybdenumdicarbonyldimer,99%;DICARBONYL(PENTAMETHYLCYCLOPENTADIENYL)MOLYBDENUM DIMER;

标识符

MDL:
MFCD00058846
InChIKey:
KOUPJJHRLAXDPP-UHFFFAOYSA-N
Inchi:
1S/2C10H15.4CO.2Mo/c2*1-6-7(2)9(4)10(5)8(6)3;4*1-2;;/h2*1-5H3;;;;;;/q2*-1;;;;;2*+1
SMILES:
C([Mo+]1234([Mo+]5678(C9(C)=C5(C)C6(C)=C7(C)[C-]89C)(C#O)C#O)([C-]5(C)C1(C)=C2(C)C3(C)=C45C)C#O)#O

羰基(五甲基环茂二烯基)钼二聚合物(12132-04-6)物化性质

实验特性

  • LogP : 2.55600
  • PSA : 0.00000
  • 沸点 : °Cat760mmHg
  • 熔点 : 188-194 °C(lit.)
  • 闪点 : °C
  • 颜色与性状 : 灰色晶体
  • 溶解性 : 未确定
  • 密度 : g/cm3

计算特性

  • 精确分子量 : 289.01300
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 578.025
  • 重原子数量 : 15
  • 复杂度 : 177
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 0
  • 互变异构体数量 : 4
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 58.2

羰基(五甲基环茂二烯基)钼二聚合物(12132-04-6)安全信息

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羰基(五甲基环茂二烯基)钼二聚合物(12132-04-6) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Pentamethylcyclopentadienylmolybdenum dicarbonyl dimer, 99%    
   CAS Registry Number:       12132-04-6    
   Formula:       [(CH3)5C5Mo(CO)2]2    
   EINECS Number:       none    
   Chemical Family:       metallocene    
   Synonym:       Permethylcyclopentadienylmolybdenum dicarbonyl dimer    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       12132-04-6       100%       10mg/m3( as Mo)       15mg/m3 (as Mo)    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation, skin, eyes    
   Eye Contact:       Causes slight or mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam.    
   If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store in a cool, dry area away from heat and direct sunlight.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red xtl.    
   Molecular Weight:       574.38    
   Melting Point:       219° dec.    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       No hazardous polymerization.    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents, reducing agents, strong acids and bases.    
   Decomposition Products:       carbon dioxide, carbon monoxide, organic fumes and molybdenum oxide.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A