12136-78-6 (硅化钼,Molybdenum disilicide)

结构式:
CAS号:
12136-78-6
中文名称:
硅化钼
英文名称:
Molybdenum disilicide
安全信息:
分子式:
MoSi2
分子量:
152.1110

硅化钼(12136-78-6)名称与标识符

名称

中文别名:
硅化钼;二硅化钼;吡咯烷-3-氨基甲酸叔丁酯;N-甲基吡咯烷酮(NMP);硅化钼靶;微纳米硅化钼;
英文别名:
Molybdenum silicide;Molybdenum disilicide;Molybdenum disiticide;1-Methyl-2-pyrrolidinone;bis(λ2-silanylidene)molybdenum;MS (silicide);Molybdenum silicide (MoSi2);molybdenum-silicide;YXTPWUNVHCYOSP-UHFFFAOYSA-N;MOLYBDENUM SILICIDE, Mo5Si3;Molybdenum silicide sputtering target, 76.2mm (3.0in) dia x 6.35mm (0.250in) thick;Molybdenum silicide sputtering target, 76.2mm (3.0in) dia x 3.18mm (0.125in) thick;Molybdenum silicide sputtering target, 50.8mm (2.0in) dia x 3.18mm (0.125in) thick;Molybdenumsilicide(MoSi2)10-50um;DTXCID401436868;EINECS 235-231-8;Molybdenum silicide (MoSi2) 10-50um;DTXSID601014284;Q2352958;Molybdenum silicide (MoSi2) 1-3um;12136-78-6;

标识符

MDL:
MFCD00151535
InChIKey:
YXTPWUNVHCYOSP-UHFFFAOYSA-N
Inchi:
1S/Mo.2Si
SMILES:
[Mo](=[Si])=[Si]

硅化钼(12136-78-6)物化性质

实验特性

  • LogP : -0.76160
  • PSA : 0.00000
  • 水溶性 : Insoluble in acids and aqua regia, however, it is soluble in HF and HNO{3}Soluble in nitric acid and hydrofluoric acid. Insoluble in water most acids.
  • 沸点 : °Cat760mmHg
  • 熔点 : 1870-2030 °C (lit.)
  • 蒸气压 : No data available
  • 闪点 : °C
  • 颜色与性状 : 在MoSi2中钼与硅之间以金属键结合,硅和硅之间则以共价键连结。二硅化钼为灰色四方晶体
  • 溶解性 : 不溶于水
  • 密度 : 6.31 g/mL at 25 °C(lit.)

计算特性

  • 精确分子量 : 153.85900
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 153.859261
  • 重原子数量 : 3
  • 复杂度 : 18.3
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

硅化钼(12136-78-6)国际标准相关数据

EINECS:
235-231-8

硅化钼(12136-78-6)参考资料

Beilstein:
235-231-8
PubChem CID:

硅化钼(12136-78-6) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Molybdenum silicide (99+%-Mo)    
   CAS Registry Number:       12136-78-6    
   Formula:       MoSi2    
   EINECS Number:       235-231-8    
   Chemical Family:       metal silicide    
   Synonym:       Molybdenum disilicide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       12136-78-6       100%       10mg/m3( as Mo)       15mg/m3 (as Mo)    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin and eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May be a mild to severe irritant to the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Do not breath dust. Inhalation of powder may lead to irritation of the respiratory tract.    
   Ingestion:       No information is available on the physiological effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes, mucous membranes and respiratory tract. Do not breath dust.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       carbon dioxide, dry powder or foam.    
   If involved in a fire, fire fighters should be equipped with NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       No hazardous combustion or decomposition products.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       No special precautions needed in handling and storage..    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       black powder    
   Molecular Weight:       152.13    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       6.31    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable.    
   Hazardous Polymerization:       No hazardous polymerization.    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A