12209-98-2 (三水锡酸钠,Sodium stannate trihydrate)

CAS号:
12209-98-2
中文名称:
三水锡酸钠
英文名称:
Sodium stannate trihydrate
分子式:
H6Na2O6Sn
分子量:
266.733582019806
简介:
三水锡酸钠为无色六角板状结晶或白色粉末,用于镀锡、锡合金、媒染剂、陶瓷、玻璃、防火织物等。

三水锡酸钠(12209-98-2)名称与标识符

名称

中文别名:
三水锡酸钠;锡酸钠,三水合物;9-溴-7,7-二甲基-7H-苯并[c]芴;三水锡(IV) 酸钠;锡酸钠;锡酸钠三水;锡酸钠 三水合物;
英文别名:
Sodium stannate trihydrate;SODIUM STANNATE(IV) TRIHYDRATE;dioxotin,sodium,trihydrate;Sodiumstannate;Sodium tin(IV) oxide trihydrate;Stannate (SnO32-),disodium,trihydrate (9CI);NJ7C1V83KG;SODIUMSTANNATETRIHYDRATE;Sodium stannate [INCI];Sodium stannate [VANDF];Disodium stannate, trihydrate;Sodium stannate(IV) trihydrate [MI];2Na.SO3n.3H2O;SFXJSNATBHJIDS-UHFFFAOYSA-N;5258AF;DISODIUM STANNATE TRIHYDRATE;disodium;dioxido(oxo)tin;trihydrate;STANNATE (SN(OH)62-),SODIUM (1:2), (OC-6-11)-;Q1665556;12209-98-2;UNII-NJ7C1V83KG;MFCD00150189;AKOS015911434;SODIUM STANNATE (IV) TRIHYDRATE;Stannate (SnO32), sodium (1:2);Stannate (SnO32), disodium;Sodium tin oxide (8CI);

标识符

MDL:
MFCD00150189
InChIKey:
SFXJSNATBHJIDS-UHFFFAOYSA-N
Inchi:
1S/2Na.3H2O.3O.Sn/h;;3*1H2;;;;/q2*+1;;;;;2*-1;
SMILES:
[Sn](=O)([O-])[O-].[Na+].[Na+].O.O.O

三水锡酸钠(12209-98-2)物化性质

实验特性

  • LogP : -0.93010
  • PSA : 90.88000
  • Merck : 14,8677
  • 水溶性 : Soluble in water. Insoluble in ethanol and acetone.
  • 沸点 : 432.4±45.0 °C at 760 mmHg
  • 熔点 : 140°C (dec.)
  • 闪点 : 215.3±28.7 °C
  • 颜色与性状 : 白色或无色结晶。
  • 溶解性 : 溶于水,不溶于乙醇和丙酮。
  • 密度 : 1.2±0.1 g/cm3

计算特性

  • 精确分子量 : 267.89800
  • 氢键供体数量 : 3
  • 氢键受体数量 : 6
  • 可旋转化学键数量 : 0
  • 同位素质量 : 267.898179g/mol
  • 重原子数量 : 9
  • 复杂度 : 18.8
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 5
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 66.2

三水锡酸钠(12209-98-2)海关数据

海关编码:
2841900090
海关数据:

中国海关编码:

2841900090

三水锡酸钠(12209-98-2)生产方法和用途

用途:
用于镀锡、锡合金、媒染剂、陶瓷、玻璃、防火织物等。
生产方法:
1.将446 kg锡(99.5%),320 kg苛性钠(90%),10...

三水锡酸钠(12209-98-2) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Sodium stannate trihydrate, min. 95%    
   CAS Registry Number:       12209-98-2    
   Formula:       Na2SnO3.3H2O    
   EINECS Number:       none    
   Chemical Family:       inorganic compound    
   Synonym:       none    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       12209-98-2       100%       2mg/m3 (as Sn)       2mg/m3 (as Sn)    

Section 3: Hazards Identification
   Emergency Overview:       Irritating to eyes, skin and respiratory tract. May be harmful if swallowed    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes slight to mild irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No information on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       Prolonged exposure to dust of tin compounds may result in benign pneumoconiosis.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       None    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a tightly sealed bottle away from moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
   Respirator:
   Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.    
   Molecular Weight:       212.68 (266.71)    
   Melting Point:       no data    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       Soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A