13116-53-5 (四氯丙烷,1,2,2,3-TETRACHLOROPROPANE)

快速询单

结构式：

四氯丙烷MOL文件

CAS号：

13116-53-5

中文名称：

四氯丙烷

英文名称：

1,2,2,3-TETRACHLOROPROPANE

安全信息：

分子式：

C₃H₄Cl₄

分子量：

181.87585735321

四氯丙烷(13116-53-5)名称与标识符

名称

中文别名：

四氯丙烷;1,2,2,3-四氯丙烷;1,2,2,3-Tetrachloropropane 1,2,2,3-四氯丙烷;磷酸四钙;

英文别名：

1,2,2,3-TETRACHLOROPROPANE;1,2,2,3-tetrachloro-propan;TECP;Propane,1,2,2,3-tetrachloro-;1,2,2,3-terachloro propane;TTCP;SCHEMBL9445641;UDPHJTAYHSSOQB-UHFFFAOYSA-;DTXSID5051656;EINECS 236-043-9;AKOS006229638;FT-0636797;Propane, 1,2,2,3-tetrachloro-;1,2,2,3-tetrachloro-propane;MFCD00039362;4-01-00-00202 (Beilstein Handbook Reference);NS00024148;T71704;CS-0329043;InChI=1/C3H4Cl4/c4-1-3(6,7)2-5/h1-2H2;13116-53-5;T0708;BRN 1734971;DTXCID9030208;DB-042006;

标识符

MDL：

MFCD00039362

InChIKey：

UDPHJTAYHSSOQB-UHFFFAOYSA-N

Inchi：

1S/C3H4Cl4/c4-1-3(6,7)2-5/h1-2H2

SMILES：

ClC(CCl)(CCl)Cl

四氯丙烷(13116-53-5)物化性质

实验特性

LogP : 2.63790
PSA : 0.00000
折射率 : 1.4920 to 1.4950
沸点 : 164°C
熔点 : -50.2°C (estimate)
溶解性 : 未确定
密度 : 1.50

计算特性

精确分子量 : 179.90700
氢键供体数量 : 0
氢键受体数量 : 0
可旋转化学键数量 : 2
同位素质量 : 179.906711g/mol
重原子数量 : 7
复杂度 : 44.9
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 2.6
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 0Å²

四氯丙烷(13116-53-5)安全信息

符号： GHS07
RTECS号： TZ7000100
危害声明：H227-H302+H312+H332-H315-H319
警示性声明：P210-P261-P264-P270-P271-P280-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P312-P305+P351+P338+P337+P313-P403+P235-P501
提示语：警告

四氯丙烷(13116-53-5)海关数据

海关编码：

2903199000

海关数据：

中国海关编码：

2903199000

概述：

2903199000 其他无环烃的饱和氯化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

四氯丙烷(13116-53-5)推荐厂家更多厂家(24)

公司名称	手机号/电话	联系人	QQ	询单
湖北鑫红利化工有限公司	15172537016 027-59503710	祝雨薇	1018283355	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
湖北摆渡化学有限公司	13517219350 13517219350	彭星	1400878899	询单
湖北成海化工有限公司	13986212397 027-59220433	张思胧	1400858822	询单
湖北实顺生物科技有限公司	15107128801 15107128801	郑雨晗	1400818899	询单
湖北信康医药化工有限公司	13476235517 13476235517	杨彩云	1438280055	询单
湖北达豪化工有限公司	13986246535	刘紫莹	1400878822	询单
巨胜化学研究院	18064118002 027-59599240	陈盼	1400838822	询单
湖北广奥生物科技有限公司	13657291602 13657291602	郭银	1098480033	询单
湖北拓邦化工有限公司	15102763473 027-59106185	涂梦婷	1400868822/1248089955	询单

四氯丙烷(13116-53-5)合成路线

合成路线：1 步

78-88-6

13116-53-5

96-19-5

反应条件：

1.1 Reagents: Chlorine ; 313 - 323 K

参考文献：

Liquid-phase chlorination of chloro olefins

Levanova, S. V.; Strizhakova, Yu. A.; Sokolov, A. B.; Aseev, E. V.; Lapidus, A. L., Khimicheskaya Tekhnologiya (Moscow, 2003, (1), 11-16

四氯丙烷(13116-53-5)参考资料

Reaxys RN：

1734971

Beilstein：

1(4)202

PubChem CID：

87576574

四氯丙烷(13116-53-5) MSDS

基础信息

1,2,2,3-Tetrachloropropane Revision number: 5
SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        1,2,2,3-Tetrachloropropane

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 4
  Flammable liquids
  HEALTH HAZARDS
    Category 4
  Acute toxicity (Oral)
  Acute toxicity (Dermal)        Category 4
    Category 4
  Acute toxicity (Inhalation)
  Skin corrosion/irritation        Category 2
    Category 2A
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
    Warning
  Signal word
  Hazard statements        Combustible liquid
    Harmful if swallowed, in contact with skin or if inhaled
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements:
    Keep away from flames and hot surfaces.
  [Prevention]
    Avoid breathing dust/fume/gas/mist/vapours/spray.
    Use only outdoors or in a well-ventilated area.
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves and eye/face protection.
  1,2,2,3-Tetrachloropropane

Section 2. HAZARDS IDENTIFICATION
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
    breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
    IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
    Rinse mouth.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Wash contaminated clothing before reuse.
    Call a POISON CENTER or doctor/physician if you feel unwell.
  [Storage]        Store in a well-ventilated place. Keep cool.
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  Components:        1,2,2,3-Tetrachloropropane
  Percent:        >95.0%(GC)
  CAS Number:        13116-53-5
  Chemical Formula:        C3H4Cl4

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Call a POISON CENTER or doctor/physician if you feel unwell.
    Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
  Skin contact:
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
  from the chemical:        generate poisonous fume.
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  1,2,2,3-Tetrachloropropane

Section 6. ACCIDENTAL RELEASE MEASURES
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapour or mist. Keep away from flames and hot surfaces. Take
    measures to prevent the build up of electrostatic charge. Use explosion-proof
    equipment. Wash hands and face thoroughly after handling.
    Use a closed system, ventilation.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
    Protective gloves.
  Hand protection:
  Eye protection:        Safety glasses. A face-shield, if the situation requires.
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
  Form:        Clear
    Colorless - Slightly pale yellow
  Colour:
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        164°C
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        1.50
  Solubility(ies):
  [Water]        No data available
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Stable under proper conditions.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
    Open flame
  Conditions to avoid:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen chloride
  products:
  1,2,2,3-Tetrachloropropane

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        skn-rbt LD50:>7940 mg/kg
    orl-rat LD50:6300 mg/kg
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available
  RTECS Number:        TZ7000100

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        48h LC50:35.43 mg/L (Oryzias latipes)
    No data available
  Crustacea:
  Algae:        No data available
  Persistence / degradability: 1 % (by BOD), 0 % (by TOC), 4 % (by GC)
  Bioaccumulative        12 - 54 (conc. 0.2 mg/L), 22 - 52 (conc. 0.02 mg/L)
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A