1317-60-8 (赤铁矿,Iron(III) oxide)

结构式:
CAS号:
1317-60-8
中文名称:
赤铁矿
英文名称:
Iron(III) oxide
分子式:
Fe2O3
分子量:
159.688202857971
简介:
赤铁矿(Hematite)化学成分为Fe2O3、属六方晶系的氧化物矿物。与等轴晶系的磁赤铁矿(γ-Fe2O3)成同质多象。单晶体常呈菱面体和板状。集合体形态多样,有片状、鳞片状(显晶质)、粒状、鲕状、肾状、土状、致密块状等。颜色呈红褐、钢灰至铁黑等色,条痕均为樱红色。金属至半金属光泽。摩斯硬度5.5~6.5,比重4.9~5.3。
呈铁黑色、金属光泽的片状赤铁矿集合体称为镜铁矿。呈灰色、金属光泽的鳞片状赤铁矿集合体称为云母赤铁矿,中国古称“云子铁”。呈红褐色、光泽暗淡的称为赭石,中国古称“代赭”,而以“赭石”泛指赤铁矿。呈鲕状或肾状的赤铁矿称为鲕状或肾状赤铁矿。
赤铁矿是自然界分布极广的铁矿物,是重要的炼铁原料,也可用作红色颜料。

2017年10月27日,世界卫生组织国际癌症研究机构公布的致癌物清单初步整理参考,赤铁矿开采(地下)(Haematite mining (underground))在一类致癌物清单中、赤铁矿在3类致癌物清单中。

赤铁矿(1317-60-8)名称与标识符

名称

中文别名:
赤铁矿;氧化铁;高导磁率氧化铁;三氧化二铁(药用);铁氧体用氧化铁;氧化铁水合物;氧化铁,黄色;α-相氧化铁;2-(2-(苄氧基羰基氨基)丙-2-基)-5-羟基-6-氧代-1,6-二氢嘧啶-4-甲酸甲酯;三氧化二铁;赤铁矿,乌钢石;磁性氧化铁红;纳米氧化铁;铁红;透明氧化铁黄;氧化铁红;质粒;红色氧化铁(III)(赤铁矿);
英文别名:
Iron(III) oxide;Ferric oxide;Iron (III) Oxide Anhydrous;diiron trioxide;E 172;Iron (III) oxide - calcined;Ironoxide anhydrous;Ironoxideredbrownpowder;Iron oxide - precipitated;Ferric oxide,medicinal;Ferric oxide for ferrite;Iron (III) oxide, red;Hematite;Iron oxide;IRON OXIDE RED;C.I.P. R.101;C.I. PIGMENT RED 101;D(-)-2-Amino-3-phosphonopropionicacid;HAEMATITE;ironore;MINETTE;miox[qr];RAW UMBER;ROUGE;SIENNA;UMBER RAW;Iron(III) oxide, red (Hematite);Iron(III)oxide,red(Hematite)(99.8%-Fe);Iron(III)oxide;CCRIS 4377;RED IRON OXIDE R 1599D;HAEMATITUM [CHP];12002-17-4;Haematite, underground mining with exposure to radon [Haematite and ferric oxide];IRON OXIDE (E172);FERRIC OXIDE RED [GREEN BOOK];HSDB 2964;FERRIC OXIDE [MI];Iron, specular;Iron(III) oxide (Fe2O3);Red Iron ORE;COSMETIC RED OXIDE;Iron ore;Hematite [WHO-DD];1317-60-8;IRON OXIDE, RED (172(II));FERRIC OXIDE [VANDF];Specularite;AKOS025296075;Haematite, underground mining with exposure to radon;IRON(III) OXIDE (E 172);EINECS 215-275-4;FERRIC OXIDE,RED [VANDF];Q103223;Iron oxide, synthetic;Q419170;FERRIC OXIDE (ANHYDROUS) [NF];IRON OXIDE REDDISH-BROWN;Blood stone;Oligist;iron(3+);oxygen(2-);Raphisiderite;Miox;Hematite (Fe2O3);EC 215-275-4;

标识符

MDL:
MFCD00011008
InChIKey:
LIKBJVNGSGBSGK-UHFFFAOYSA-N
Inchi:
1S/2Fe.3O/q2*+3;3*-2
SMILES:
[Fe+3].[Fe+3].[O-2].[O-2].[O-2]

赤铁矿(1317-60-8)物化性质

实验特性

  • LogP : -0.36140
  • PSA : 0.00000
  • 熔点 : 1538 °C
  • 闪点 : >230 °F
  • 颜色与性状 : 外观为有金属光泽的紫褐色或紫灰色粉末
  • 溶解性 : 不溶于水
  • 密度 : 5.24

计算特性

  • 精确分子量 : 159.85500
  • 氢键供体数量 : 0
  • 氢键受体数量 : 3
  • 可旋转化学键数量 : 0
  • 同位素质量 : 159.854615g/mol
  • 重原子数量 : 5
  • 复杂度 : 0
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 5
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 3Ų

赤铁矿(1317-60-8)国际标准相关数据

EINECS:
215-275-4

赤铁矿(1317-60-8)海关数据

海关编码:
2601111000
海关数据:

中国海关编码:

2601111000

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赤铁矿(1317-60-8)相关文献

赤铁矿(1317-60-8) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Iron (III) oxide, red (Hematite) (99.8%-Fe)    
   CAS Registry Number:       1317-60-8    
   Formula:       Fe2O3    
   EINECS Number:       215-275-4    
   Chemical Family:       metal oxide    
   Synonym:       Haematite, Iron ore. Red iron oxide. Ferric oxide.    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       1317-60-8       100%       5mg/m3       10mg/m3    

Section 3: Hazards Identification
   Emergency Overview:       May be irritating to skin and eyes and respiratory tract.    
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       May be a mild to severe irritant to the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Do not breath dust. Inhalation of powder may lead to irritation of the respiratory tract.    
   Ingestion:       No information available on the effects of ingestion.    
   Acute Health Affects:       May be irritating to skin, eyes, mucous membranes and respiratory tract. Do not breath dust.    
   Chronic Health Affects:       Prolonged inhalation of iron oxide dust can produce a benign pneumoconiosis known as siderosis.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       material is non-flammable    
   Special Fire Fighting Procedures:       No special fire-fighting procedures. The material is non-flammable.    
   Hazardous Combustion and       no hazardous decomposition products.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       No special storage conditions.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   If in the form of a fine dust and ventilation is not available, a respirator should be worn. The use of respirators
   Respirator:
   requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       red pwdr.    
   Molecular Weight:       159.69    
   Melting Point:       1565°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       none    
   Solubility in Water:       insoluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable solid    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       Powdered aluminum, hydrazine, ethylene oxide, calcium hypochlorite and magnesium    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No specific information available in the RTECS files.    
   Carcinogenic Effects:       No data available    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A