13537-24-1 (高氯酸铁水合物,iron triperchlorate)

高氯酸铁水合物;高氯酸铁;无水高氯酸铁;伊班膦酸-d3钠盐;高氯酸铁(3+);高氯酸铁六水合物;高氯酸铁 水合物, REAGENT GRADE;

iron triperchlorate;iron(3+),triperchlorate;ferric iron triperchlorate ion;FERRIC PERCHLORATE,HYDRATED;Iron(3+) perchloric acid salt;IRON(III) PERCHLORATE HYDRATE;Perchloric acid,iron(3+) salt;Fe(ClO4)3;IRON PERCHLORATE;FERRIC PERCHLORATE;IRON(III) PERCHLORATE;iron perchlorate-hydrate;Perchloric acid,iron salt;IRON(+3)PERCHLORATE HYDRATE;Perchloric acid, iron salt;Perchloricacid,iron(3+)salt;Q22289678;Perchloric acid, iron(3+) salt (3:1);Perchloric acid,iron(3+) salt (3:1);EINECS 236-908-0;Perchloric acid, iron(3+) salt;13537-24-1;iron(3+);triperchlorate;J-008873;DTXSID50890670;NS00085330;LHOWRPZTCLUDOI-UHFFFAOYSA-K;Iron (III) perchlorate;DTXCID901030976;

QQVZFIHPKOCZIT-UHFFFAOYSA-N

1S/3ClO4.Fe/c3*2-1(3,4)5;/q3*-1;+3

[Fe+3].[Cl+3]([O-])([O-])([O-])[O-].[Cl+3]([O-])([O-])([O-])[O-].[Cl+3]([O-])([O-])([O-])[O-]

236-908-0

将新沉淀的Fe(OH)3在水浴上，加入稍过量的70％ HClO4，装上回流冷凝器加热。10h后，大部分Fe(OH)3溶解，用水稀释并将溶液过滤。滤液在水浴上蒸发。结晶经抽滤，用CHCl3洗涤（除去HClO4）。粗产品收率95％。用水重结晶三次，抽滤。在装有CaCl2的干燥器中干燥得产品十水合高氯酸铁，收率72％。将十水合物置于浓H2SO4或P2O5的干燥器中干燥得六水合物。