13568-45-1 (钨酸锂,Lithium tungstate)

结构式:
CAS号:
13568-45-1
中文名称:
钨酸锂
英文名称:
Lithium tungstate
分子式:
Li2O4W
分子量:
261.719596862793
简介:
钨酸锂是化学物质,分子式:Li2WO4,英文名:Lithium Tungstate,无色三角晶体,可通过在Li(OH)或Li2CO3溶液中溶解WO3而制得Li2WO4。易溶于水,在酸中分解,不溶于乙醇。在500~800℃温度下加热用H2还原成钨青铜,在加热到600℃后生成WO2,最终产物是W(β型)。

钨酸锂(13568-45-1)名称与标识符

名称

中文别名:
钨酸锂;钨酸锂 min;硫酸羟铝;氧化钨锂;钨酸锂, 99%最低;钨酸锂, 99% MIN;
英文别名:
Lithium tungstate;Lithiumtungstatewhitepowder;dilithium wolframate;dilithium,dioxido(dioxo)tungsten;Lithium tungsten oxide;AC1NN4QG;AC1O1FVC;Dilithium tetraoxotungstate Lithium tungsten oxide;diLithoTab tungstate;Dilithium tetraoxotungstate;TUNGSTEN OXIDE;Tungstic acid dilithium salt;Ditungstic acid dilithium salt;Lithiumtungstate,98%;Lithium tungstate 98%;Tungstate (WO42-), dilithium, (T-4)-;Lithium tungstate, 98%;MFCD00016185;Lithium Tungsten Powder;13568-45-1;dilithium;dioxido(dioxo)tungsten;dilithium(1+) tungstate;

标识符

MDL:
MFCD00016185
InChIKey:
SCKKBXOJPMZVPF-UHFFFAOYSA-N
Inchi:
1S/2Li.4O.W/q2*+1;;;2*-1;
SMILES:
[W](=O)(=O)([O-])[O-].[Li+].[Li+]

钨酸锂(13568-45-1)物化性质

实验特性

  • LogP : -0.47520
  • PSA : 80.26000
  • 水溶性 : Soluble in water.
  • 沸点 : °Cat760mmHg
  • 熔点 : 742°C
  • 闪点 : °C
  • 颜色与性状 : 具有BeSiO3石晶格。无色三角晶。
  • 溶解性 : 可溶解的
  • 密度 : 3.71 g/mL at 25 °C(lit.)

计算特性

  • 精确分子量 : 261.96300
  • 氢键供体数量 : 2
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 0
  • 同位素质量 : 261.962599
  • 重原子数量 : 7
  • 复杂度 : 62.2
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 3
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 80.3

钨酸锂(13568-45-1)安全信息

钨酸锂(13568-45-1)国际标准相关数据

EINECS:
236-978-2

钨酸锂(13568-45-1)生产方法和用途

生产方法:
在Li(OH)或Li2CO3溶液中溶解WO3而制得Li2WO4。

钨酸锂(13568-45-1)推荐厂家 更多厂家(35)

公司名称手机号/电话联系人QQ微信询单
湖北拓邦化工有限公司 15102763473
027-59106185
涂梦婷 1400868822/1248089955
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上海源叶生物科技有限公司 15026964105
15026964105
汤思磊 2881489226
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湖北方德新材料有限公司 18086096695邱经理 1462312301
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湖北摆渡化学有限公司 13517219350
13517219350
彭星 1400878899
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上海瀚思化工有限公司 18939883912
021-34536277
顾经理 3003949364
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巨胜化学研究院 18064118002
027-59599240
陈盼 1400838822
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广东元丰化学试剂有限公司 13380732450
0751-2829979
元丰化学小郑 3828157387
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湖北巨胜科技有限公司 18871490354王珊 1400848866
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北京索莱宝科技有限公司 18101056239
010-50973130
龚思雨 3193328036
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上海创赛科技有限公司 15021221957
021-59553580
凌度 2852351983
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钨酸锂(13568-45-1)相关文献

钨酸锂(13568-45-1) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Lithium tungstate, 98%    
   CAS Registry Number:       13568-45-1    
   Formula:       Li2WO4    
   EINECS Number:       236-978-2    
   Chemical Family:       metal tungstate    
   Synonym:       Tungstic acid dilithium salt    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       13568-45-1       100%       1mg/m3 (as W)       no data    

Section 3: Hazards Identification
   Lithium in soluble form is toxic to the central nervous system and on repeated ingestion may damage kidneys
   Emergency Overview:
   and act as a teratogen
   Primary Routes of Exposure:       Ingestion    
   Eye Contact:       May cause slight to mild irritation of the eyes.    
   Skin Contact:       May cause slight to mild irritation of the skin.    
   Inhalation:       Do not breath dust. May be irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.    
   Soluble lithium is toxic to the central nervous system. May be irritating to skin, eyes and respiratory tract. It is
   Acute Health Affects:
   unknown if lithium tungstate will form soluble lithium in the gastrointestinal system.
   Chronic Health Affects:       May cause kidney damage. May be a teratogen.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
   Special Fire Fighting Procedures:
   breathing apparatus and full protective clothing.
   Hazardous Combustion and       None    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a tightly sealed bottle away from moisture.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
   Respirator:
   Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white to off-white powder    
   Molecular Weight:       261.73    
   Melting Point:       742°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       3.71    
   Odor:       none    
   Solubility in Water:       soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       none    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A