14452-66-5 (一氧化磷,Phosphorus oxide (PO)(6CI,7CI,8CI,9CI))

快速询单

结构式：

一氧化磷MOL文件

CAS号：

14452-66-5

中文名称：

一氧化磷

英文名称：

Phosphorus oxide (PO)(6CI,7CI,8CI,9CI)

分子式：

分子量：

46.9731607437134

一氧化磷(14452-66-5)名称与标识符

名称

中文别名：

一氧化磷;

英文别名：

Phosphorus oxide (PO)(6CI,7CI,8CI,9CI);Oxophosphinyl;phosphoryl;Phosphorus oxide;Phosphorus monoxide;Phosphorus oxide (po);CHEBI:29315;PO(.);oxidophosphorus(.);oxophosphanyl;DTXSID601337149;14452-66-5;

标识符

InChIKey：

LFGREXWGYUGZLY-UHFFFAOYSA-N

Inchi：

1S/OP/c1-2

SMILES：

[P]=O |^1:0|

一氧化磷(14452-66-5)物化性质

实验特性

PSA : 17.07

计算特性

精确分子量 : 47.97653
氢键供体数量 : 0
氢键受体数量 : 1
可旋转化学键数量 : 0
同位素质量 : 46.968676617g/mol
重原子数量 : 2
复杂度 : 2
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : -0.7
拓扑分子极性表面积 : 17.1Å²

一氧化磷(14452-66-5)相关文献

1. Decarboxylative cross-coupling reactions for P(O)–C bond formation
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4. Recent trends in the direct oxyphosphorylation of C–C multiple bonds
Alireza Bakhtiary,Mohammad Reza Poor Heravi,Akbar Hassanpour,Issa Amini,Esmail Vessally RSC Adv. 2021 11 470
5. A monocyclic phosphorane oxide anion and the extraordinary reactivity of its tautomeric phosphine oxide alkoxide
Itshak Granoth,Rivka Alkabets,Ezra Shirin J. Chem. Soc. Chem. Commun. 1981 981
6. Copper-catalyzed tandem phosphination–decarboxylation–oxidation of alkynyl acids with H-phosphine oxides: a facile synthesis of β-ketophosphine oxides
Pengbo Zhang,Liangliang Zhang,Yuzhen Gao,Jian Xu,Hua Fang,Guo Tang,Yufen Zhao Chem. Commun. 2015 51 7839
7. Copper-catalyzed aerobic oxidative coupling of ketones with P(O)–H compounds leading to β-ketophosphine oxides
Qiang Fu,Dong Yi,Zhijie Zhang,Wu Liang,Suyuan Chen,Lu Yang,Qiang Zhang,Jianxin Ji,Wei Wei Org. Chem. Front. 2017 4 1385
8. An efficient preparation of β-ketophosphine oxides from alkynylphosphine oxides with benzaldehyde oxime as a hydroxide source
Lu-Lu Chen,Jing-Wen Zhang,Wan-Wan Yang,Pei Chen,Dan-Yun Chen,Yan-Bo Wang Org. Biomol. Chem. 2019 17 3003
9. X-ray crystallographic, luminescence and NMR studies of phenacyldiphenylphosphine oxide with the Ln(iii) ions Sm, Eu, Gd, Tb and Dy
Erin G. Leach,Justin R. Shady,Adam C. Boyden,Anne-lise Emig,Alyssa T. Henry,Emily K. Connor,Richard J. Staples,Stephanie Schaertel,Eric J. Werner,Shannon M. Biros Dalton Trans. 2017 46 15458
10. Reduction of secondary and tertiary phosphine oxides to phosphines
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