14552-35-3 (亚乙基二胺铜络合物,Cupriethylenediamine Hydroxide (1.0 M in H2O))

CAS号:
14552-35-3
中文名称:
亚乙基二胺铜络合物
英文名称:
Cupriethylenediamine Hydroxide (1.0 M in H2O)
安全信息:
分子式:
C4H18CuN4O2
分子量:
217.757321834564

亚乙基二胺铜络合物(14552-35-3)名称与标识符

名称

中文别名:
双氢氧化乙二胺铜;Boc-D-3,3-二苯基丙氨酸;双氢氧化乙二胺铜(II);铜乙二胺;亚乙基二胺铜;亚乙基二胺铜溶液;氢氧化双(乙二胺)铜;双(乙二胺)氢氧化铜;亚乙基二胺铜络合物;氢氧化乙二胺铜混合溶液;二乙二胺氢氧化铜络合溶液;双氢氧化乙二胺铜/铜乙二胺;
英文别名:
Copper(2+),bis(1,2-ethanediamine-kN1,kN2)-, hydroxide (1:2), (SP-4-1)-;COPPER(II)-ETHYLENEDIAMINE COMPLEX 1M SOLUTION IN WATER;CUPRIETHYLENEDIAMINE;Cupriethylenediamine Hydroxide (1.0 M in H2O);Bis(ethylenediamine)copper(II) hydroxide;Copper ethylenediamine;Copper(II)-ethylenediame complex;Copper(II)-ethylenediamine complex;Cupriethylenediamine dihydroxide;CUPRIETHYLENEDIAMINE SOLUTION;COPPER(II) ETHYLENEDIAMINE;CUPRIETHYLENEDIAMINE SOLUTION, 1M;CUPRIETHYLENEDIAMINE SOLUTION, 0.5M;STRAY LIGHT FILTER(390NM) RSPEC0036;

标识符

InChIKey:
WATCRQGYOIZIHC-UHFFFAOYSA-L
Inchi:
1S/2C2H8N2.Cu.2H2O/c2*3-1-2-4;;;/h2*1-4H2;;2*1H2/q;;+2;;/p-2
SMILES:
[Cu+2].[OH-].[OH-].NCCN.NCCN

亚乙基二胺铜络合物(14552-35-3)物化性质

实验特性

  • LogP : -0.25070
  • PSA : 24.06000
  • 沸点 : 119.7°Cat760mmHg
  • 闪点 : >110℃
  • 浓度 : 1.0 M in H2O
  • 颜色与性状 : 深蓝色液体
  • 溶解性 : 未确定
  • 密度 : 1.086 g/mL at 25 °C

计算特性

  • 精确分子量 : 120.98300
  • 氢键供体数量 : 4
  • 氢键受体数量 : 6
  • 可旋转化学键数量 : 2
  • 同位素质量 : 183.067098
  • 重原子数量 : 11
  • 复杂度 : 6
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 5
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 104

亚乙基二胺铜络合物(14552-35-3)安全信息

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亚乙基二胺铜络合物(14552-35-3) MSDS

基础信息

Name:Copper(II)-Ethylenediamine Complex for Viscosity Determination of Material Safety Data Sheet
Synonym:None
CAS:14552-35-3
Section 1 - Chemical Product ? MSDS Name:Copper(II)-Ethylenediamine Complex for Viscosity Determination of Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
14552-35-3COPPER(II)-ETHYLENEDIAMINE100238-597-7
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic:
None

Section 4 - FIRST AID MEASURES
? Eyes: Get medical aid immediately. Do NOT allow victim to rub eyes or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Keep container tightly closed. Do not get on skin or in eyes. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14552-35-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: clear dark blue
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.1000g/cm3
Molecular Formula: C2Cu2H8N2-n
Molecular Weight: 159.148

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, oxidizers.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 14552-35-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
COPPER(II)-ETHYLENEDIAMINE - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8 (6.1)
UN Number: 1761
Packing Group: II
IMO
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8 (6.1)
UN Number: 1761
Packing Group: II
RID/ADR
Shipping Name: CUPRIETHYLENEDIAMINE SOLUTION
Hazard Class: 8
UN Number: 1761
Packing group: II

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14552-35-3: No information available.
Canada
CAS# 14552-35-3 is listed on Canada's NDSL List.
CAS# 14552-35-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14552-35-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A