151-51-9 (聚碳化二亚胺,Methanediimine (9CI))

    Version 1.3
    Regulation (EC) No 1907/2006

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    1 - Product and Company Information

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    Product Name        POLYCARBODIIMIDE, 50 WT. % SOLUTION IN    
    PROPYLENE GLYCOL METHYL ETHER ACETATE

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    2 - Hazards Identification

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    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    May impair fertility. Flammable. Harmful by inhalation, in contact
    with skin and if swallowed. Irritating to eyes, respiratory system
    and skin.

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    3 - Composition/Information on Ingredients

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    Product Name        CAS #        EC no        Annex I    
    Index Number
    POLYCARBODIIMIDE, 50 WT. %        None        None        None    
    SOLUTION INPROPYLENE GLYCOL
    METHYL ETHER ACETATE
    Formula        CH2N2    

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    4 - First Aid Measures

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    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician immediately.

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    5 - Fire Fighting Measures

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    EXTINGUISHING MEDIA
    Suitable: For small (incipient) fires, use media such as
    "alcohol" foam, dry chemical, or carbon dioxide. For large
    fires, apply water from as far as possible. Use very large
    quantities (flooding) of water applied as a mist or spray; solid
    streams of water may be ineffective. Cool all affected
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    containers with flooding quantities of water.
    SPECIAL RISKS
    Specific Hazard(s): Combustible liquid. Emits toxic fumes under
    fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

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    6 - Accidental Release Measures

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    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear respirator, chemical safety goggles, rubber boots, and
    heavy rubber gloves.
    METHODS FOR CLEANING UP
    Absorb on sand or vermiculite and place in closed containers for
    disposal. Ventilate area and wash spill site after material
    pickup is complete.

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    7 - Handling and Storage

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    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Avoid
    contact with eyes, skin, and clothing. Avoid prolonged or
    repeated exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Keep away from heat
    and open flame. Store in a cool dry place.

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    8 - Exposure Controls / Personal Protection

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    ENGINEERING CONTROLS
    Mechanical exhaust required. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash contaminated clothing before reuse. Wash thoroughly after
    handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Special Protective Measures: Wear appropriate government approved
    respirator, chemical-resistant gloves, safety goggles, other
    protective clothing.

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    9 - Physical and Chemical Properties

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    pH N/A
    BP/BP Range        154,000 °C    
    MP/MP Range        N/A    
    Flash Point        46,000 °C        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        1,0300 g/cm3    
    Partition Coefficient N/A
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    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

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    10 - Stability and Reactivity

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    STABILITY
    Stable: Stable.
    Conditions of Instability: Moisture.
    Conditions to Avoid: Moisture.
    Materials to Avoid: Strong acids.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Nitrogen oxides.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur

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    11 - Toxicological Information

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    SENSITIZATION
    Sensitization: Prolonged or repeated exposure may cause allergic
    reactions in certain sensitive individuals.
    SIGNS AND SYMPTOMS OF EXPOSURE
    Exposure can cause: Narcotic effect. Lung irritation, chest
    pain, and edema which may be fatal. CNS depression. Dermatitis.
    Gastrointestinal disturbances. Contact with eyes may cause
    blindness. To the best of our knowledge, the chemical, physical,
    and toxicological properties have not been thoroughly
    investigated.
    ROUTE OF EXPOSURE
    Skin Contact: Causes skin irritation.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: Causes eye irritation. Can cause blindness.
    Warning: exposure to vapor may cause eye injury, the onset of
    which may be delayed for several hours. Avoid all exposure to
    eyes.
    Inhalation: May be harmful if inhaled. Material is irritating to
    mucous membranes and upper respiratory tract.
    Ingestion: May be harmful if swallowed.
    TARGET ORGAN INFORMATION
    Nerves. Liver. Kidneys.
    CHRONIC EXPOSURE - REPRODUCTIVE HAZARD
    Result: Overexposure may cause reproductive disorder(s) based on
    tests with laboratory animals.

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    12 - Ecological Information

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    No data available.

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    13 - Disposal Considerations

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    SUBSTANCE DISPOSAL
    This combustible material may be burned in a chemical incinerator
    equipped with an afterburner and scrubber. Observe all federal,
    state, and local environmental regulations.

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    14 - Transport Information

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    RID/ADR
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    IMDG
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 1993
    Class: 3
    PG: III
    Proper Shipping Name: Flammable liquid, n.o.s.
    Inhalation Packing Group I: No
    Technical Name: Required

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    15 - Regulatory Information

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    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: T
    Toxic.
    R-PHRASES: 60-10-20/21/22-36/37/38
    May impair fertility. Flammable. Harmful by inhalation, in
    contact with skin and if swallowed. Irritating to eyes,
    respiratory system and skin.
    S-PHRASES: 53-16-26-36/37/39-45
    Avoid exposure - obtain special instructions before use. Keep
    away from sources of ignition - no smoking. In case of contact
    with eyes, rinse immediately with plenty of water and seek
    medical advice. Wear suitable protective clothing, gloves, and
    eye/face protection. In case of accident or if you feel unwell,
    seek medical advice immediately (show the label where possible).
    Caution: Substance not yet fully tested (EU).

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    16 - Other Information

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    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
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    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    ALDRICH        www.molbase.com    

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SECTION 16 - ADDITIONAL INFORMATION
N/A