15522-71-1 (三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III),Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III))

快速询单

结构式：

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)MOL文件

CAS号：

15522-71-1

中文名称：

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)

英文名称：

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III)

分子式：

C₃₃H₅₇EuO₆

分子量：

701.766095876694

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)名称与标识符

名称

中文别名：

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III);三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)[核磁共振位移试剂];三(2,2,6,6-四甲基-3,5-庚二酸)铕;三(2,2,6,6-四甲基-3,5-庚二酮)铕(III);三(2,2,6,6-四甲基-3,5-庚二酮酸)铕;左洛啡烷;

英文别名：

Resolve-Al EuTMHD;Eu(tmhd)3;Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europi um(III);Eu(dpm)3;Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III);Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-, (OC-6-11)-;NSC 147451;Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-.kappa.O,.kappa.O')-, (OC-6-11)-;EINECS 239-565-5;Europium tris(2,2,6,6-tetramethyl-3,5-heptanedionate);Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium;Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-kappaO3,kappaO5)-, (OC-6-11)-;(Dipivalomethanato)europium(III);DTXSID601015363;Tris(2,2,6,6-tetramethylheptane-3,5-dionato-O,O')europium;Tris(dipivalomethanato)europium;EUROPIUM(III)-DPM;15522-71-1;Tris(dipivaloylmethanato)europium;Europium(III) 2,2,6,6-tetramethylheptane-3,5-dione;Europium, tris(2,2,6,6-tetramethyl-3,5-heptanedionato-kappaO,kappaO')-, (OC-6-11)-;europium(3+);(Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-olate;

标识符

MDL：

MFCD00000019

InChIKey：

DVUACRCEVJAWMS-LWTKGLMZSA-K

Inchi：

1S/3C11H20O2.Eu/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;

SMILES：

[Eu+3].[O-]/C(=C\C(C(C)(C)C)=O)/C(C)(C)C.[O-]/C(=C\C(C(C)(C)C)=O)/C(C)(C)C.[O-]/C(=C\C(C(C)(C)C)=O)/C(C)(C)C

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)物化性质

实验特性

LogP : 7.82070
PSA : 102.42000
沸点 : 275°C
熔点 : 188.0 to 192.0 deg-C
闪点 : No data available
颜色与性状 : 未确定
溶解性 : 未确定
敏感性 : Hygroscopic
密度 : No data available

计算特性

精确分子量 : 705.36000
氢键供体数量 : 0
氢键受体数量 : 6
可旋转化学键数量 : 9
同位素质量 : 702.337
重原子数量 : 40
复杂度 : 199
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 4
互变异构体数量 : 4
表面电荷 : 0
拓扑分子极性表面积 : 120

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)安全信息

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)国际标准相关数据

EINECS：

239-565-5

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)海关数据

海关编码：

2914509090

海关数据：

中国海关编码：

2914509090

概述：

2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途, 丙酮报明包装

Summary：

HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)推荐厂家更多厂家(21)

公司名称	手机号/电话	联系人	QQ	询单
巨胜化学研究院	18064118002 027-59599240	陈盼	1400838822	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
天门恒昌化工有限公司	15102714773 027-59322316	雷经理	1178380033	询单
湖北广奥生物科技有限公司	13657291602	郭银	1098480033	询单
湖北信康医药化工有限公司	13476235517 13476235517	杨彩云	1438280055	询单
湖北鑫红利化工有限公司	15172537016 027-59503710	祝雨薇	1018283355	询单
湖北齐飞医药化工有限公司	18702762251 027-59322506	刘经理：18702762251	1438980033	询单
湖北实顺生物科技有限公司	15107128801 027-59223025	郑雨晗	1400818899	询单
湖北永阔科技有限公司	18064098002 027-59223108	孙瑶	1248580055	询单
湖北摆渡化学有限公司	18871490324 027-59106051	彭星	1400878899	询单

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1)参考资料

Reaxys RN：

Beilstein：

T162857

PubChem CID：

87577039

三(2,2,6,6-四甲基-3,5-庚二酮酸)铕(III)(15522-71-1) MSDS

基础信息

  Tris(2,2,6,6-tetramethyl-3,5-      Revision number: 5
  heptanedionato)europium(III) [NMR Shift Reagent]
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent]

  Revision number:        5

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS        Not classified
    Not classified
  HEALTH HAZARDS
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols        None
  Signal word        No signal word
  Hazard statements        None
  Precautionary statements:        None

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
    Substance
  Substance/mixture:
  Components:        Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)europium(III) [NMR Shift Reagent]
    ....
  Percent:
  CAS Number:        15522-71-1
    Eu(dpm)3 , Europium(III) Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)
  Synonyms:
  Chemical Formula:        C33H57EuO6

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
    Get medical advice/attention if you feel unwell. Rinse mouth.
  Ingestion:
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
    Dry chemical, foam, water spray, carbon dioxide.
  Suitable extinguishing
  media:
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

Section 5. FIRE-FIGHTING MEASURES
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store under inert gas.
    Protect from moisture.
    Store away from incompatible materials such as oxidizing agents.
    Hygroscopic
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid
    Crystal- Powder
  Form:
  Colour:        Pale yellow - Yellow
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:190°C
  Boiling point/range:        No data available
    No data available
  Flash point:
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        No data available
  Solubility(ies):
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
[Water] No data available
[Other solvents] No data available

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide
  products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  NTP =        No data available
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
    No data available
  Crustacea:
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
    No data available
  Henry's Law
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Tris(2,2,6,6-tetramethyl-3,5-
  heptanedionato)europium(III) [NMR Shift
  Reagent]

SECTION 16 - ADDITIONAL INFORMATION
N/A