16832-21-6 (1,2-O-亚环己基-a-D-呋喃葡萄糖,1,2-O-Cyclohexylidene-a-D-glucofuranose)

快速询单

结构式：

1,2-O-亚环己基-a-D-呋喃葡萄糖MOL文件

CAS号：

16832-21-6

中文名称：

1,2-O-亚环己基-a-D-呋喃葡萄糖

英文名称：

1,2-O-Cyclohexylidene-a-D-glucofuranose

分子式：

C₁₂H₂₀O₆

分子量：

260.283604621887

1,2-O-亚环己基-a-D-呋喃葡萄糖(16832-21-6)名称与标识符

名称

中文别名：

1,2-O-亚环己基-α-D-呋喃葡萄糖;1,2-葡萄糖环己酮;6-O-(三异丙基甲硅烷基)-D-半乳醛;伪-D-Glucofuranose,1,2-O-cyclohexylidene-;1,2-O-亚环己基-a-D-呋喃葡萄糖;1,2-O-环亚己基-Α-D-呋喃葡萄糖;

英文别名：

(R)-1-((3a'R,5'R,6'S,6a'R)-6'-Hydroxytetrahydrospiro[cyclohexane-1,2'-furo[2,3-d][1,3]dioxol]-5'-yl)ethane-1,2-diol;(1R)-1-[(3aR,5R,6S,6aR)-6-hydroxyspiro[3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole-2,1'-cyclohexane]-5-yl]ethane-1,2-diol;NULL;1,2,O-Cyclohexylidenglucofuranose;1,2-O-Cyclohexylidene-;1,2-O-CYCLOHEXYLIDENE-ALPHA-D-GLUCOFURANOSE;A-D-glucofuranose;1,2-O-Cyclohexylidene--D-Glucofuranose;1,2-O-cyclohexylidene-a-D-glucofuranose;1,2-O-Cyclohexylidine-a-D-glucofuranose;1,2-O-CYCLOHEXYLIDENE-ALPHA-D-GLUCOFURA&;1-O,2-O-Cyclohexylidene-α-D-glucofuranose;1,2-O-Cyclohexylidene-α-D-glucofuranose ,98%;1,2-O-Cyclohexylidene-alpha-D-glucofuranose,98%;1,2-O-CYCLOHEXYLIDENE-ALPHA-D-GLUCOFURANOSE 98%;DTXSID80369228;16832-21-6;1,2-O-Cyclohexylidene- alpha -D-glucofuranose;AKOS016007906;alpha-D-Glucofuranose, 1,2-O-cyclohexylidene-;(R)-1-((3a'R,5'R,6'S,6a'R)-6'-hydroxytetrahydrospiro[cyclohexane-1,2'-furo[3,2-d][1,3]dioxole]-5'-yl)ethane-1,2-diol;a-D-Glucofuranose,1,2-O-cyclohexylidene-;1,2-O-Cyclohexylidene-alpha-D-glucofuranose, 95%;(1R)-1-[(3'AR,5'R,6'S,6'AR)-6'-HYDROXY-TETRAHYDROSPIRO[CYCLOHEXANE-1,2'-FURO[2,3-D][1,3]DIOXOL]-5'-YL]ETHANE-1,2-DIOL;1,2-O-Cyclohexane-1,1-diyl-alpha-D-xylo-hexofuranose;

标识符

MDL：

MFCD00142481

InChIKey：

KAUCUKASFLXURN-RCZSTQMZSA-N

Inchi：

1S/C12H20O6/c13-6-7(14)9-8(15)10-11(16-9)18-12(17-10)4-2-1-3-5-12/h7-11,13-15H,1-6H2/t7-,8+,9-,10-,11-/m1/s1

SMILES：

O1[C@@H]2[C@H]([C@@H]([C@@H](CO)O)O[C@@H]2OC21CCCCC2)O

1,2-O-亚环己基-a-D-呋喃葡萄糖(16832-21-6)物化性质

实验特性

LogP : -0.49880
PSA : 88.38000
折射率 : 1.5230 (estimate)
沸点 : 363.54°C (rough estimate)
熔点 : 163-168 °C (lit.)
颜色与性状 : 液体
溶解性 : 未确定
密度 : 1.2377 (rough estimate)

计算特性

精确分子量 : 260.12600
氢键供体数量 : 3
氢键受体数量 : 6
可旋转化学键数量 : 2
同位素质量 : 260.12598835g/mol
重原子数量 : 18
复杂度 : 303
同位素原子数量 : 0
确定原子立构中心数量 : 5
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 0.7
拓扑分子极性表面积 : 88.4Å²

1,2-O-亚环己基-a-D-呋喃葡萄糖(16832-21-6)安全信息

WGK Germany： 3
安全术语： S24/25
安全说明： S24/25
风险术语： R36/37/38
危险品运输编号： NONH for all modes of transport
危险类别码： 36/37/38

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1,2-O-亚环己基-a-D-呋喃葡萄糖(16832-21-6)相关文献

1. Subject index 1966
Chem. Commun. (London) 1966 934

1,2-O-亚环己基-a-D-呋喃葡萄糖(16832-21-6) MSDS

基础信息

Name:	1 2-O-Cyclohexylidene-Alpha-D-Glucofuranose 98% Material Safety Data Sheet
Synonym:	None Known
CAS:	16832-21-6

Section 1 - Chemical Product ? MSDS Name:1 2-O-Cyclohexylidene-Alpha-D-Glucofuranose 98% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
16832-21-6	1,2-O-Cyclohexylidene-Alpha-D-Glucofur	98%	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 16832-21-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Needles
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 152.00 - 155.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C12H20O6
Molecular Weight: 260.28

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 16832-21-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,2-O-Cyclohexylidene-Alpha-D-Glucofuranose - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 16832-21-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 16832-21-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 16832-21-6 is not listed on the TSCA inventory.
It is for research and development use only.

SECTION 16 - ADDITIONAL INFORMATION
N/A