16919-18-9 (六氟磷酸盐,Phosphate(1-),hexafluoro-)

快速询单

结构式：

六氟磷酸盐MOL文件

CAS号：

16919-18-9

中文名称：

六氟磷酸盐

英文名称：

Phosphate(1-),hexafluoro-

分子式：

F₆P

分子量：

144.964181900024

六氟磷酸盐(16919-18-9)名称与标识符

名称

中文别名：

S-(1-氧代-2-吡啶)巯基-1,3-二甲基丙基脲六氟磷酸盐;六氟磷酸盐;

英文别名：

Phosphate(1-),hexafluoro-;HEXAFLUOROPHOSPHATE;Hexafluorophosphate(1-) ion;UNII-8JV86J4A30;[PF6]-1;Ammonium hexafluorophosphate(1-);NSC407930;Hexafluorophosphate ion;Q2786508;PF6(-);InChI=1/F6P/c1-7(2,3,4,5)6/q-;hexafluoro-;hexafluoridophosphate(1-);Phosphate(1-), potassium;hexafluoro-lambda(5)-phosphanuide;Ammonium phosphorus fluoride;BDBM36130;16919-18-9;Potassium hexafluorophosphate (KPF6);CHEMBL181124;PF6-;8JV86J4A30;NSC403554;CHEBI:30201;E?-phosphanuide;NSC404039;[PF6](-);LJQLCJWAZJINEB-UHFFFAOYSA-N;NS00114996;hexafluorophosphate(1-);Phosphate(1-), hexafluoro-;Phosphate(1-), ammonium;AMY25801;

标识符

InChIKey：

LJQLCJWAZJINEB-UHFFFAOYSA-N

Inchi：

1S/F6P/c1-7(2,3,4,5)6/q-1

SMILES：

[P-](F)(F)(F)(F)(F)F

六氟磷酸盐(16919-18-9)物化性质

实验特性

PSA : 0

计算特性

精确分子量 : 144.9642
氢键供体数量 : 0
氢键受体数量 : 0
可旋转化学键数量 : 0
同位素质量 : 144.96418097g/mol
重原子数量 : 7
复杂度 : 62.7
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 3.2
拓扑分子极性表面积 : 0Å²

六氟磷酸盐(16919-18-9)推荐厂家更多厂家(3)

公司名称	手机号/电话	联系人	QQ	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
南通润丰石油化工有限公司	19952847550 0513-66017696	曹海燕	2143087160	询单
深圳市瑞吉特生物科技有限公司	15813841136 0755-89459231	钦先生	1029374309	询单

六氟磷酸盐(16919-18-9)合成路线

合成路线：1 步

反应条件：

1.1

< 100 °C; 7 h, 100 °C; 100 °C → rt
1.2

Reagents:

Pivaloyl chloride

;
rt
1.3

Reagents:

Potassium hydroxide

Solvents:

Water

;
3 h, rt
1.4

Reagents:

Hexafluorophosphoric acid

Solvents:

Water

参考文献：

Chemische Berichte (1994'Novel, very strong, uncharged auxiliary bases; design and synthesis of monomeric and polymer-bound triaminoiminophosphorane bases of broadly varied steric demand' Schwesinger, Reinhard; Willaredt, Juergen; Schlemper, Helmut; Keller, Manfred; Schmitt, Dieter; et al, 1994 , vol.127(12), # 4 p.2435-54

合成路线：1 步

34311-90-5

_81%

16919-18-9

700795-41-1

反应条件：

1.1 Reagents: Potassium hexafluorophosphate Solvents: Water ; 6 h, 25 °C

参考文献：

Thermo- and pH-responsive poly(ionic liquid) membranes

Chen, Fei; Guo, Jiangna; Xu, Dan; Yan, Feng, Polymer Chemistry, 2016, 7(6), 1330-1336

合成路线：1 步

_76%

参考文献：

Impact of substituents attached to N-heterocyclic carbenes on the catalytic activity of copper complexes in the reduction of carbonyl compounds with triethoxysilane

Peng, Jiajian; Chen, Lingzhen; Xu, Zheng; Hu, Yingqian; Li, Jiayun; et al, Chinese Journal of Chemistry, 2009, 27(11), 2121-2124

合成路线：1 步

34311-90-5

_60%

16919-18-9

700795-41-1

反应条件：

1.1 Reagents: Potassium hexafluorophosphate Solvents: Water ; 24 h, rt

参考文献：

CO2 Responsive Imidazolium-Type Poly(Ionic Liquid) Gels

Zhang, Jing; Xu, Dan; Guo, Jiangna; Sun, Zhe; Qian, Wenjing; et al, Macromolecular Rapid Communications, 2016, 37(14), 1194-1199

合成路线：1 步

657394-63-3

16919-18-9

700795-41-1

反应条件：

1.1 Reagents: Sodium hexafluorophosphate Solvents: Water ; rt; 1 d, rt

参考文献：

Efficient synthesis of styrene carbonate from CO2 and styrene oxide using zinc catalysts immobilized on soluble imidazolium-styrene copolymers

Qiao, Kun; Ono, Fumitaka; Bao, Quanxi; Tomida, Daisuke; Yokoyama, Chiaki, Journal of Molecular Catalysis A: Chemical, 2009, 303(1-2), 30-34

合成路线：1 步

16919-18-9

700795-41-1

参考文献：

An efficient Heck reaction in water catalyzed by palladium nanoparticles immobilized on imidazolium-styrene copolymers

Qiao, Kun; Sugimura, Rie; Bao, Quanxi; Tomida, Daisuke; Yokoyama, Chiaki, Catalysis Communications, 2008, 9(15), 2470-2474

合成路线：1 步

反应条件：

1.1 Solvents: Acetonitrile

参考文献：

Preparation, photochemistry, and electronic structures of coumarin laser dye complexes of cyclopentadienylruthenium(II)

Koefod, Robert S.; et al, Inorganic Chemistry, 1989, 28(12), 2285-90

合成路线：1 步

74173-48-1

_61%

16919-18-9

75675-24-0

反应条件：

1.1 Reagents: Ruthenium trichloride

参考文献：

Novel synthesis and characterization of ruthenium tris(4-methyl-4'-vinyl-2,2'-bipyridine) complexes

Williams, C. E.; Lowry, R. B.; Braven, J.; Belt, S. T., Inorganica Chimica Acta, 2001, 315(1), 112-119

合成路线：1 步

反应条件：

1.1 Solvents: Acetonitrile

参考文献：

Preparation, photochemistry, and electronic structures of coumarin laser dye complexes of cyclopentadienylruthenium(II)

Koefod, Robert S.; et al, Inorganic Chemistry, 1989, 28(12), 2285-90

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Iridium trichloride Solvents: 2-Methoxyethanol , Water ; overnight, 120 °C; 120 °C → rt
1.2 Solvents: Ethylene glycol ; 15 h, 150 °C; 0 °C; 5 min, 0 °C → 85 °C
1.3 Reagents: Ammonium hexafluorophosphate Solvents: Water

参考文献：

Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis

Singh, Anuradha; Teegardin, Kip; Kelly, Megan; Prasad, Kariate S.; Krishnan, Sadagopan; et al, Journal of Organometallic Chemistry, 2015, 776, 51-59

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Iridium trichloride Solvents: Ethylene glycol ; 1 min, rt; 50 min, 200 °C; 200 °C → rt
1.2 30 min, 200 °C
1.3 Reagents: Ammonium hexafluorophosphate Solvents: Water ; cooled

参考文献：

Microwave-assisted synthesis of heteroleptic Ir(III)+ polypyridyl complexes

Monos, Timothy M.; Sun, Alexandra C.; McAtee, Rory C.; Devery, James J.; Stephenson, Corey R. J., Journal of Organic Chemistry, 2016, 81(16), 6988-6994

合成路线：1 步

_79%

反应条件：

1.1 Solvents: Methanol ; overnight, reflux; reflux → rt
1.2 Reagents: Ammonium hexafluorophosphate ; 1 h, rt

参考文献：

Green-emitting iridium(III) complexes containing sulfanyl- or sulfone-functionalized cyclometallating 2-phenylpyridine ligands

Constable, Edwin C.; Ertl, Cathrin D.; Housecroft, Catherine E.; Zampese, Jennifer A., Dalton Transactions, 2014, 43(14), 5343-5356

合成路线：1 步

_72%

反应条件：

1.1 Solvents: Ethylene glycol ; 24 h, 150 °C; 150 °C → rt
1.2 Reagents: Ammonium hexafluorophosphate Solvents: Water

参考文献：

Scrutinizing Design Principles toward Efficient, Long-Term Stable Green Light-Emitting Electrochemical Cells

Namanga, Jude E.; Gerlitzki, Niels; Mudring, Anja-Verena, Advanced Functional Materials, 2017, 27(17),

合成路线：1 步

_50%

反应条件：

1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran ; 0 °C; 12 h, 22 °C
1.2 Solvents: Dichloromethane ; 12 h, 50 °C; 50 °C → 22 °C
1.3 Reagents: Lithium aluminum hydride Solvents: Tetrahydrofuran ; 0 °C; 30 min, 0 °C; 14 h, 80 °C; 80 °C → 22 °C
1.4 Reagents: Potassium sodium tartrate Solvents: Water ; cooled; 4 h, 22 °C
1.5 Reagents: Hydrochloric acid Solvents: Diethyl ether , Methanol ; 30 min, 0 °C
1.6 Solvents: Toluene ; 14 h, 90 °C; 90 °C → 22 °C
1.7 Reagents: Potassium hexafluorophosphate Solvents: Water ; 2 h, 22 °C

参考文献：

Multifunctional organoboron compounds for scalable natural product synthesis

Meng, Fanke; McGrath, Kevin P.; Hoveyda, Amir H., Nature (London, 2014, 513(7518), 367-374

合成路线：1 步