169749-99-9 ((3S)-(+)-1-苄基-3-(甲氨基)吡咯烷,(3S)-1-benzyl-N-methylpyrrolidin-3-amine)

快速询单

结构式：

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷MOL文件

CAS号：

169749-99-9

中文名称：

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷

英文名称：

(3S)-1-benzyl-N-methylpyrrolidin-3-amine

安全信息：

分子式：

C₁₂H₁₈N₂

分子量：

190.284722805023

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)名称与标识符

名称

中文别名：

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷;(S)-N-苄基-3-甲氨基吡咯烷;(3S)-(+)-1-苄基-3-(甲氨基)吡啶烷;(3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine (3S)-(+)-1-苄基-3-(甲氨基)吡啶烷;(3S)-(＋)-1-苄基-3-(甲胺基)吡咯烷;(S)-1-苄基-3-甲氨基吡咯烷;（S）-1-苄基-3-甲胺基吡咯烷;2-氨基-4,6-二甲基嘧啶;(3S)-(+)-1-苄基-3- 甲氨基吡啶烷;

英文别名：

(S)-1-Benzyl-3-methylaminopyrrolidine;(S)-N-Benzyl-3-methylaminopyrrolidine;(3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine;(3S)-1-benzyl-N-methylpyrrolidin-3-amine;(S)-1-benzyl-N-methylpyrrolidin-3-amine;(3S)-1-Benzyl-N-methyl-3-pyrrolidinamine;(S)-(1-Benzyl-pyrrolidin-3-yl)-methyl-amine;(S)-1-Benzyl-3-(methylamino)pyrrolidine;3-Pyrrolidinamine, N-methyl-1-(phenylmethyl)-, (3S)-;PubChem11213;(3S)-1-benzyl-N-methyl-pyrrolidin-3-amine;Jsp003462;UEAYAIWNQQWSBK-LBPRGKRZSA-N;FCH920609;ZI;

标识符

MDL：

MFCD00191310

InChIKey：

UEAYAIWNQQWSBK-LBPRGKRZSA-N

Inchi：

1S/C12H18N2/c1-13-12-7-8-14(10-12)9-11-5-3-2-4-6-11/h2-6,12-13H,7-10H2,1H3/t12-/m0/s1

SMILES：

N1(CC2C=CC=CC=2)CC[C@@H](C1)NC

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)物化性质

实验特性

LogP : 1.80910
PSA : 15.27000
折射率 : 3 ° (C=10, EtOH)
沸点 : 273℃ at 760 mmHg
闪点 : 105.62℃
颜色与性状 : Yellow to Brown Sticky Oil to Semi-Solid
溶解性 : 未确定
密度 : 0.990(lit.)

计算特性

精确分子量 : 190.14700
氢键供体数量 : 1
氢键受体数量 : 2
可旋转化学键数量 : 3
重原子数量 : 14
复杂度 : 164
同位素原子数量 : 0
确定原子立构中心数量 : 1
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 1.5
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 15.3

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)安全信息

符号： GHS05
危险品标志： Xn
危险品运输编号： 2735
危害声明：H314
警示性声明：P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501
提示语：危险
储存条件： 2-8 °C
PackingGroup： III
危险类别码： 22-52
信号词： Warning
HazardClass： 8

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)海关数据

海关编码：

2933990090

海关数据：

中国海关编码：

2933990090

概述：

2933990090. 其他仅含氮杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

申报要素：

品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

Summary：

2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)推荐厂家更多厂家(19)

公司名称	手机号/电话	联系人	QQ	询单
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金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)上下游

(S)-3-(N-Boc-甲胺)吡咯烷 (S)-1-苄基-3-吡咯烷醇 (S)-N-苄基吡咯-3-甲醇对甲苯磺酸酯 (R)-N-苄基吡咯-3-甲醇对甲苯磺酸酯一甲胺

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9)参考资料

Reaxys RN：

5850780

Beilstein：

S161306

PubChem CID：

87564486

(3S)-(+)-1-苄基-3-(甲氨基)吡咯烷(169749-99-9) MSDS

基础信息

(3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: (3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS
    Category 1C
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 1
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Danger
  Hazard statement        Causes severe skin burns and eye damage
  Precautionary statements
  [Prevention]        Do not breathe.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
    breathing.
    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    Wash contaminated clothing before reuse.
    Immediately call a POISON CENTER or doctor/physician.
    Store locked up.
  [Storage]
  [Disposal]        Dispose of contents/container through a waste management company authorized by
    the local government

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Component(s):        (3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine
    >98.0%(GC)
  Percent:
  CAS Number:        169749-99-9
  Chemical Formula:        C12H18N2

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. Immediately call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing.Immediately call a POISON CENTER or
    doctor/physician.
  Ingestion:        Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
    induce vomiting.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, carbon dioxide.
  media:
  Extinguishing media not to Water (It may scatter and spread fire.)
  be used:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
    When extinguishing fire, be sure to wear personal protective equipment.
  Special protective
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use extra personal protective equipment (self-contained breathing apparatus). Keep
  Personal precautions,
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
  containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
  up: material should be promptly disposed of, in accordance with appropriate laws and
    regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapor or mist. Wash hands and face thoroughly after handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapor or aerosol
    will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store under inert gas.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection:        Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Hand protection:        Impervious gloves.
  Eye protection:        Safety goggles. A face-shield, if the situation requires.
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
    clear
  Form:
  Color:        Colorless - Very pale yellow
  Odor:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling Point/Range:        No data available
  Flash Point:        No data available
  Explosive limits
    No data available
  Lower:
  Upper:        No data available
  Density:        0.99
  Solubility:        No data available

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
  Reactivity:        No special reactivity has been reported.
  Conditions to avoid:        Air-sensitive
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx)
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        8: Corrosive.
  UN-No:        2735
  Proper shipping name:        Polyamines, liquid, corrosive, n.o.s.
  Packing group:        III

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A