173831-50-0 (R-2,2'-双(甲氧基甲氧基)-1,1'-联萘,(R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl)

CAS号:
173831-50-0
中文名称:
R-2,2'-双(甲氧基甲氧基)-1,1'-联萘
英文名称:
(R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl
安全信息:
分子式:
C24H22O4
分子量:
374.429087162018

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)名称与标识符

名称

中文别名:
R-2,2'-双(甲氧基甲氧基)-1,1'-联萘;R-(+)-2,2′-双(甲氧基甲氧基)-1,1′-联萘;(R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘;(R)-(+)-2,2'-双(甲氧基甲氧基)-1,1'-联萘;(R)-(+)-2,2′-双(甲氧基甲氧基)-1,1′-联萘;(R)-(+)-2,2'-双(甲氧甲氧基)-1,1'-联萘;(R)-(+)-2,2'-双(羟乙氧基)-1,1'-二萘;(R)-2,2’-双(甲氧基甲氧基)-1,1’-联萘;(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl (R)-2,2'-双(甲氧基甲氧基)-1,1'-联萘;3-氨基-6-氯-2-吡嗪甲腈;R-2,2’-双(甲氧基甲氧基)-1,1’-联萘;(R)-(+)-2,2-双(甲氧甲基)-1,1-二萘酚;
英文别名:
1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-;(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl;(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene;(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene;(R)-(+)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-2,2’-Bis(methoxymethoxy)-1,1'-binaphthyl;(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl;(R)-2,2’-Bis(methoxymethoxy)-1,1’-binaphthyl;-2,2'-Bis(methoxymethoxy);(R)-(+)-2,2'-Bis(methoxymethox;(R)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAP&;2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHALENE;R-2,2'-Bis(methoxymethoxyl)-1,1'-binaphthyl;(S)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;(R)-(+)-2,2-Bis(Methoxymethoxy)-1,1-Binaphthyl;(S)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene;(S)-(-)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL;C24H22O4;2-(methoxymethoxy)-1-[2-(methoxymethoxy)naphthalen-1-yl]naphthalene;S;J-010946;SY009990;FT-0663336;10.14272/YIAQRNNJNMLGTP-UHFFFAOYSA-N.1;SY009989;2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene, 97%;B3203;AKOS015911249;CS-W011783;(S)-(-)-2,2 inverted exclamation mark -Bis(methoxymethoxy)-1,1 inverted exclamation mark -binaphthalene;(R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene, 97%;AC9224;(S)-(-)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene, 97%;A885237;173831-50-0;142128-92-5;74292-20-9;B3202;C73331;(R)-(+)-2,2/'-BIS(METHOXYMETHOXY)-1,1/'-BINAPHTHYL;SCHEMBL1446528;(S)-(-)-2,2?-BIS(METHOXYMETHOXY)-1,1?-BINAPHTHALENE;doi:10.14272/YIAQRNNJNMLGTP-UHFFFAOYSA-N.1;2-(methoxymethoxy)-1-[2-(methoxymethoxy)-1-naphthyl]naphthalene;DS-14105;1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-, (1R)-;CS-0031335;(R)-(+)-2,2 inverted exclamation mark -Bis(methoxymethoxy)-1,1 inverted exclamation mark -binaphthalene;(R)-2 pound not2 inverted exclamation mark -Bis(methoxymethoxy)-1 pound not1 inverted exclamation mark -binaphthyl;DB-346391;(S)-2,2\\'-Bis(methoxymethoxy)-1,1\\'-binaphthalene;(S)-(-)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene;633-997-1;634-273-8;

标识符

MDL:
MFCD03788935
InChIKey:
YIAQRNNJNMLGTP-UHFFFAOYSA-N
Inchi:
1S/C24H22O4/c1-25-15-27-21-13-11-17-7-3-5-9-19(17)23(21)24-20-10-6-4-8-18(20)12-14-22(24)28-16-26-2/h3-14H,15-16H2,1-2H3
SMILES:
O(COC)C1C=CC2C=CC=CC=2C=1C1=C(C=CC2C=CC=CC1=2)OCOC

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)物化性质

实验特性

  • LogP : 5.62540
  • PSA : 36.92000
  • 沸点 : 477.8±45.0 ºC (760 Torr),
  • 熔点 : 100.0 to 104.0 deg-C
  • 闪点 : 126.2±35.6 ºC,
  • 溶解度 : Insuluble (1.3E-3 g/L) (25 ºC),
  • 颜色与性状 : 无可用
  • 溶解性 : 无可用
  • 比旋光度 : +85° (c 0.22, CHCl3)
  • 光学活性 : [α]20/D +92°, c = 1% in chloroform
  • 密度 : 1.182±0.06 g/cm3 (20 ºC 760 Torr),

计算特性

  • 精确分子量 : 374.15200
  • 氢键供体数量 : 0
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 7
  • 同位素质量 : 374.15180918g/mol
  • 重原子数量 : 28
  • 复杂度 : 428
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 5.9
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 36.9

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)安全信息

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R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)上下游

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)相关文献

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0)参考资料

Reaxys RN:
15590148
PubChem CID:

R-2,2'-双(甲氧基甲氧基)-1,1'-联萘(173831-50-0) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       (R)-(+)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl, 98%    
   CAS Registry Number:       173831-50-0    
   Formula:       C24H22O4    
   EINECS Number:       none    
   Chemical Family:       organic alcohol    
   Synonym:       (R)-(+)-2,2'-Bis-methoxymethoxy-[1,1']binaphthalenyl    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title compound       173831-50-0       100%       no data       no data    

Section 3: Hazards Identification
   Emergency Overview:       Dust is irritating to the respiratory tract, skin, eyes. May be harmful if swallowed.    
   Primary Routes of Exposure:       Ingestion, eyes, inhalation    
   Eye Contact:       Causes mild to moderate irritation of the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   Inhalation:       Dust is irritating to the nose, mucous membranes and respiratory tract.    
   Ingestion:       No specific information is available on the physiological effects of ingestion.    
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.    
   Chronic Health Affects:       No information available on long-term chronic effects.    
   NTP:       No    
   IARC:       No    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       no data    
   Autoignition Temperature:       no data    
   Explosion Limits:       no data    
   Extinguishing Medium:       dry chemical, carbon dioxide, water or foam.    
   If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide.    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
   Small spills can be mixed with vermiculite, sodium carbonate or other suitable non-combustible adsorbent and
   Spill and Leak Procedures:
   swept up.

SECTION 7: Handling and Storage
   Handling and Storage:       Store the material in a tightly sealed container in a cool, dry place.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear protective clothing and gloves.    
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
   Respirator:
   Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white powder    
   Molecular Weight:       374.43    
   Melting Point:       100-103°    
   Boiling Point:       no data    
   Vapor Pressure:       no data    
   Specific Gravity:       no data    
   Odor:       not determined    
   Solubility in Water:       slightly soluble    

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       none    
   Incompatibility:       oxidizing agents    
   Decomposition Products:       carbon monoxide, carbon dioxide and organic fumes.    

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.    
   Carcinogenic Effects:       no data    
   Mutagenic Effects:       no data    
   Tetratogenic Effects:       no data    

SECTION 12: Ecological Information
   Ecological Information:       No information available    

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous    
   Hazard Class (CFR):       NA    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       NA    
   UN ID Number (CFR):       NA    
   Shipping Name (IATA):       Non-hazardous    
   Hazard Class (IATA):       NA    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       NA    
   UN ID Number (IATA):       NA    

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory.    
   SARA (Title 313):       Title compound not listed.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A