18117-29-8 (苄基三苯基磷硼氢化物,Benzyltriphenylphosphonium borohydride)

CAS号:
18117-29-8
中文名称:
苄基三苯基磷硼氢化物
英文名称:
Benzyltriphenylphosphonium borohydride
分子式:
C25H22BP
分子量:
364.226947307587

苄基三苯基磷硼氢化物(18117-29-8)名称与标识符

名称

中文别名:
4-溴-3-甲基-5-硝基吡啶;苯基三苯基磷氢硼化物;苄基三苯基磷硼氢化物;
英文别名:
Benzyltriphenylphosphonium borohydride;benzyl(triphenyl)phosphanium,boranuide;AC1MBYVN;18117-29-8;SCHEMBL989761;Phosphonium, triphenyl(phenylmethyl)-, tetrahydroborate(1-) (1:1);benzyl(triphenyl)phosphanium;boron(1-);SCHEMBL989760;Benzyltriphenylphosphonium tetrahydroborate;Benzyltriphenylphosphoniumtetrahydroborate;DTXSID90369911;Benzyl Triphenylphosphonium Boro-Hydride;

标识符

InChIKey:
ICVMMQSETPKHRH-UHFFFAOYSA-N
Inchi:
1S/C25H22P.B/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;/q+1;-1
SMILES:
[P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)CC1C=CC=CC=1.[B-]

苄基三苯基磷硼氢化物(18117-29-8)物化性质

实验特性

  • LogP : 3.99680
  • PSA : 13.59000
  • 熔点 : 157-163 °C
  • 颜色与性状 : 无可用
  • 溶解性 : 无可用

计算特性

  • 精确分子量 : 367.17900
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 5
  • 同位素质量 : 364.1552179g/mol
  • 重原子数量 : 27
  • 复杂度 : 347
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0Ų

苄基三苯基磷硼氢化物(18117-29-8)安全信息

苄基三苯基磷硼氢化物(18117-29-8)推荐厂家 更多厂家(2)

公司名称手机号/电话联系人QQ微信询单
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苄基三苯基磷硼氢化物(18117-29-8) MSDS

基础信息

Name:Benzyltriphenylphosphonium borohydride 98% Material Safety Data Sheet
Synonym:
CAS:18117-29-8
Section 1 - Chemical Product ? MSDS Name:Benzyltriphenylphosphonium borohydride 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
18117-29-8Benzyltriphenylphosphonium borohydride98%unlisted
Hazard Symbols: C
Risk Phrases: 15 34

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Contact with water liberates extremely flammable gases. Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. May react with acids or moisture to form explosive hydrogen gas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. DO NOT USE WATER!

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
? Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep away from strong acids. Keep away from water. Water free area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 18117-29-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 160 - 163 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C25H22P.BH4
Molecular Weight: 368.27

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, oxides of boron, phosphorous fumes.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 18117-29-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzyltriphenylphosphonium borohydride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.*
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: II
IMO
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3 (8)
UN Number: 3131
Packing Group: II
RID/ADR
Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.
Hazard Class: 4.3
UN Number: 3131
Packing group: II

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 15 Contact with water liberates extremely
flammable gases.
R 34 Causes burns.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 18117-29-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 18117-29-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 18117-29-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A