18156-67-7 ((2-溴乙基)三甲基硅烷,(2-Bromoethyl)trimethylsilane)

快速询单

结构式：

(2-溴乙基)三甲基硅烷MOL文件

CAS号：

18156-67-7

中文名称：

(2-溴乙基)三甲基硅烷

英文名称：

(2-Bromoethyl)trimethylsilane

安全信息：

分子式：

C₅H₁₃BrSi

分子量：

181.146221876144

(2-溴乙基)三甲基硅烷(18156-67-7)名称与标识符

名称

中文别名：

(2-溴乙基)三甲基硅烷;(2-溴乙基)三甲硅烷(含稳定剂碳酸氢钠);(2-Bromoethyl)trimethylsilane (stabilized with Silver chip) (2-溴乙基)三甲硅烷(含稳定剂碳酸氢钠);(2-溴乙基)三甲基硅烷 (含稳定剂银屑);2-(三乙基硅烷基)溴乙烷;2-(三乙基硅烷基)溴乙烷 (含稳定剂银屑);

英文别名：

(2-Bromoethyl)trimethylsilane;2-(Trimethylsilyl)ethyl bromide;(2-Bromoethyl)trimethylsilane (stabilized with Silver chip);(2-Bromoethyl)trimethylsilane (stabilized with NaHCO3);2-bromoethyl(trimethyl)silane;(2-bromoethyl)(trimethyl)silane;BrCH2CH2SiMe3;Silane,(2-bromoethyl)trimethyl;2-(Trimethylsilyl)ethyl Bromide (stabilized with Silver chip);FT-0744760;AKOS006228000;J-500664;2-Bromoethyltrimethylsilane;SCHEMBL2231221;B2216;E78074;(2-Bromoethyl)trimethyl-silane;A880986;MFCD03093623;DTXSID00470244;Silane, (2-bromoethyl)trimethyl-;EN300-219021;BS-53156;SY057908;18156-67-7;DA-17597;HYRIFSNOTHOUQJ-UHFFFAOYSA-N;

标识符

MDL：

MFCD03093623

InChIKey：

HYRIFSNOTHOUQJ-UHFFFAOYSA-N

Inchi：

1S/C5H13BrSi/c1-7(2,3)5-4-6/h4-5H2,1-3H3

SMILES：

BrCC[Si](C)(C)C

(2-溴乙基)三甲基硅烷(18156-67-7)物化性质

实验特性

LogP : 2.71950
PSA : 0.00000
沸点 : 149.6±13.0 °C at 760 mmHg
蒸气压 : 5.1±0.3 mmHg at 25°C
闪点 : 46.8±14.8 °C
颜色与性状 : 不确定
溶解性 : 不确定
密度 : 1.15

计算特性

精确分子量 : 179.99700
氢键供体数量 : 0
氢键受体数量 : 0
可旋转化学键数量 : 2
同位素质量 : 179.99699g/mol
重原子数量 : 7
复杂度 : 46.5
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 无
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 0Å²

(2-溴乙基)三甲基硅烷(18156-67-7)安全信息

符号： GHS02 GHS05
安全术语： S26-36/37/39
安全说明： S26
风险术语： R34
危险品运输编号： UN 3265
危害声明：H226-H314
警示性声明：P210-P233-P240-P241+P242+P243-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P405-P501
提示语：危险
储存条件： 0-10°C
PackingGroup： III
危险类别码： 34
信号词： warning

(2-溴乙基)三甲基硅烷(18156-67-7)国际标准相关数据

EINECS：

(2-溴乙基)三甲基硅烷(18156-67-7)海关数据

海关编码：

2931900090

海关数据：

中国海关编码：

2931900090

概述：

2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

Summary：

2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

(2-溴乙基)三甲基硅烷(18156-67-7)推荐厂家更多厂家(22)

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(2-溴乙基)三甲基硅烷(18156-67-7)上下游

三甲基硅乙醇乙烯基三甲基硅烷

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(2-溴乙基)三甲基硅烷(18156-67-7)参考资料

Reaxys RN：

1732285

PubChem CID：

11665502

(2-溴乙基)三甲基硅烷(18156-67-7) MSDS

基础信息

  (2-Bromoethyl)trimethylsilane (stabilized with Silver      Revision number: 6
  chip)
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        (2-Bromoethyl)trimethylsilane (stabilized with Silver chip)

  Revision number:        6

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 3
  Flammable liquids
  HEALTH HAZARDS
    Category 1C
  Skin corrosion/irritation
  Serious eye damage/eye irritation        Category 1
  ENVIRONMENTAL HAZARDS        Not classified
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Danger
    Flammable liquid and vapour
  Hazard statements
    Causes severe skin burns and eye damage
  Precautionary statements:
  [Prevention]        Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
    Keep container tightly closed.
    Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
    measures against ignition by the static discharge and the spark.
    Do not breathe dust/fume/gas/mist/vapours/spray.
    Wash hands thoroughly after handling.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
    breathing.
    IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse
    skin with water/shower.
    Wash contaminated clothing before reuse.
    Immediately call a POISON CENTER or doctor/physician.
    Store in a well-ventilated place. Keep cool.
  [Storage]
    Store locked up.
  Silver chip)

Section 2. HAZARDS IDENTIFICATION
[Disposal] Dispose of contents/container through a waste management company authorized by
the local government.

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Components:        (2-Bromoethyl)trimethylsilane (stabilized with Silver chip)
    >98.0%(T)
  Percent:
  CAS Number:        18156-67-7
    2-(Trimethylsilyl)ethyl Bromide (stabilized with NaHCO3)
  Synonyms:
  Chemical Formula:        C5H13BrSi

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Immediately call a POISON CENTER or doctor/physician.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
    soap and water. Immediately call a POISON CENTER or doctor/physician.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing.Immediately call a POISON CENTER or
    doctor/physician.
    Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT
  Ingestion:
    induce vomiting.
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Unsuitable extinguishing Solid streams of water
  media:
  Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
    generate poisonous fume.
  from the chemical:
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
    spraying with water. Eliminate all ignition sources if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use extra personal protective equipment (self-contained breathing apparatus). Keep
  protective equipment and people away from and upwind of spill/leak. Ensure adequate ventilation. Entry to non-
  emergency procedures: involved personnel should be controlled around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into an
  containment and cleaning airtight container. In case of large amount of spillage, contain a spill by bunding.
  up: Adhered or collected material should be promptly disposed of, in accordance with
    appropriate laws and regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.

Section 7. HANDLING AND STORAGE
Precautions for safe handling
Silver chip)

Section 7. HANDLING AND STORAGE
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.
    Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
    surfaces. -No smoking. Take measures to prevent the build up of electrostatic
    charge. Use explosion-proof equipment. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
    May develop pressure. Open carefully.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in an explosion-poof refregerator.
    Store under inert gas.
    Protect from moisture.
    Store locked up.
    Store away from incompatible materials such as oxidizing agents.
    Heat-sensitive, Moisture-sensitive
  Packaging material:        Comply with laws.

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Half or full facepiece respirator, self-contained breathing apparatus(SCBA), supplied
    air respirator, etc. Use respirators approved under appropriate government standards
    and follow local and national regulations.
  Hand protection:        Impervious gloves.
  Eye protection:        Safety goggles. A face-shield, if the situation requires.
  Skin and body protection: Impervious protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid
    Clear
  Form:
  Colour:        Colorless - Slightly pale yellow
  Odour:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        No data available
  Flash point:        No data available
  Flammability or explosive
  limits:
  Lower:        No data available
  Upper:        No data available
  Relative density:        1.15
  Solubility(ies):
  [Water]        No data available
  [Other solvents]        No data available

Section 10. STABILITY AND REACTIVITY
    Stable under proper conditions.
  Chemical stability:
  Possibility of hazardous No special reactivity has been reported.
  reactions:
  Conditions to avoid:        Spark, Open flame, Static discharge
  Incompatible materials: Oxidizing agents, Strong acids
  Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide, Silicon oxides
  products:
  Silver chip)

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
    No data available
  NTP =
  Reproductive toxicity:        No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        3: Flammable liquid.
  Subsidiary risk:        8: Corrosive.
  UN-No:        2924
  Proper shipping name:        Flammable liquid, corrosive, n.o.s.
  Packing group:        III

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.
  Silver chip)

SECTION 16 - ADDITIONAL INFORMATION
N/A