18911-76-7 (六氟乙酰丙酮化钇,YTTRIUM HEXAFLUOROACETYLACETONATE)

快速询单

结构式：

六氟乙酰丙酮化钇MOL文件

CAS号：

18911-76-7

中文名称：

六氟乙酰丙酮化钇

英文名称：

YTTRIUM HEXAFLUOROACETYLACETONATE

分子式：

C₁₅H₃F₁₈O₆Y

分子量：

710.057841539383

六氟乙酰丙酮化钇(18911-76-7)名称与标识符

名称

中文别名：

六氟乙酰丙酮化钇;六氟-乙酰丙酮钇;六氟-乙酰丙酮钇(III);2,5-呋喃二甲醇;

英文别名：

YTTRIUM HEXAFLUOROACETYLACETONATE;YTTRIUM(III) HEXAFLUORO-2,4-PENTANEDIONATE;YTTRIUM(III)HEXAFLUOROACETYLACETONATE;YTTRIUM HEXAFLUOROPENTANEDIONATE;Yttrium(lll) hexafluoroacetylacetonate;1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate,yttrium(3+);YTTRIUM HEXAFLUORO-2,4-PENTANEDIONATE;Yttrium(III) hexafluoroacetylacetonate,Y(CF3COCHCOCF3)3;Yttriumhexafluoroacetylacetonate98%;Yttrium hexafluoroacetylacetonate 98%;Yttrium(III) hexafluoroacetylacetonate 98%;Yttrium hexafluoroacetylacetonate (99.9%-Y) (REO);1,1,1,5,5,5-hexafluoro-4-oxo-2-penten-2-olate; yttrium(3+);18911-76-7;DTXSID90380767;1,1,1,5,5,5-hexafluoro-4-oxopent-2-en-2-olate;yttrium(3+);A813302;1,1,1,5,5,5-hexakis(fluoranyl)-4-oxidanylidene-pent-2-en-2-olate; yttrium(3+);yttrium(3+) tris(1,1,1,5,5,5-hexafluoro-2,4-dioxopentan-3-ide);

标识符

MDL：

MFCD00064764

InChIKey：

VJOUMINOGFSOBW-UHFFFAOYSA-K

Inchi：

1S/3C5H2F6O2.Y/c3*6-4(7,8)2(12)1-3(13)5(9,10)11;/h3*1,12H;/q;;;+3/p-3

SMILES：

[Y+3].FC(C(=CC(C(F)(F)F)=O)[O-])(F)F.FC(C(=CC(C(F)(F)F)=O)[O-])(F)F.FC(C(=CC(C(F)(F)F)=O)[O-])(F)F

六氟乙酰丙酮化钇(18911-76-7)物化性质

实验特性

LogP : 6.13470
PSA : 78.90000
沸点 : 240°C
熔点 : 166-170°C
闪点 : 22.8°C
颜色与性状 : 白色晶体。
溶解性 : 不确定
密度 : g/cm3

计算特性

精确分子量 : 709.87000
氢键供体数量 : 0
氢键受体数量 : 6
可旋转化学键数量 : 12
同位素质量 : 709.87
重原子数量 : 40
复杂度 : 210
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 3
共价键单元数量 : 4
疏水参数计算参考值（XlogP） : 无
互变异构体数量 : 无
表面电荷 : 0
拓扑分子极性表面积 : 120A^2

六氟乙酰丙酮化钇(18911-76-7)安全信息

六氟乙酰丙酮化钇(18911-76-7)生产方法和用途

生产方法：

将按反应摩尔比计算量的六氟乙酰丙酮铵的乙醚溶液与氯化钇的水溶液混合并搅拌。得到的六氟乙酰丙酮钇螯合物进入乙醚层中。乙醚溶液用无水硫酸钠干燥后，蒸去乙醚，得到粗产品。可用水甲醇(9∶1)混合溶剂重结晶纯化。得到的纯品很可能是六氟乙酰丙酮钇的二水合物。若将上述产品在P2O5存在下，于室温及3Pa压力下干燥72h，可得到无水的六氟乙酰丙酮钇。

六氟乙酰丙酮化钇(18911-76-7)推荐厂家更多厂家(7)

公司名称	手机号/电话	联系人	QQ	询单
赫澎（上海）生物科技有限公司	13122891558 186-16545970	张硕	3418426269	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
上海麦克林生化科技股份有限公司	15221275939 021-50706066	沈经理	269348414	询单
天成化工（江苏）有限公司	15251950002 0512-83500002	陈小姐		询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单

六氟乙酰丙酮化钇(18911-76-7) MSDS

基础信息

Section 1: Product Identification
   Chemical Name:       Yttrium hexafluoroacetylacetonate, hydrate (99.9%-Y) (REO)
   CAS Registry Number:       18911-76-7
   Formula:       Y(CF3COCHCOCF3)3.XH2O
   EINECS Number:       none
   Chemical Family:       metal fluorobeta-diketonate complexes
   Synonym:       Yttrium(III) hexafluoro 2,4-pentanedionate

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 18911-76-7 100% 1mg/m3 as Y 1mg/m3 as Y

Section 3: Hazards Identification
   Emergency Overview:       Irritating to skin, eyes and respiratory tract.
   Primary Routes of Exposure:       Ingestion, inhalation
   Eye Contact:       Causes slight to mild irritation of the eyes
   Skin Contact:       Causes slight to mild irritation of the skin.
   Inhalation:       Irritating to the nose, mucous membranes and respiratory tract.
   Ingestion:       No information available on the physiological effects of ingestion.
   Acute Health Affects:       Irritating to skin, eyes and respiratory tract.
   Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate
   Chronic Health Affects:       fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth
   structure, kidney and liver damage.
   NTP:       No
   IARC:       No
   OSHA:       No

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
   Inhalation:
   breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable
   Autoignition Temperature:       none
   Explosion Limits:       none
   Extinguishing Medium:       carbon dioxide, dry powder or foam
   If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
   Special Fire Fighting Procedures:
   self-contained breathing apparatus and full protective clothing.
   Hazardous Combustion and       If involved in a fire this material may emit toxic organic fumes.
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage: Store the material in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
   Respirator:
   requires a Respiratory Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.
   Additional Protection:       No additional protection required.

SECTION 9: Physical and Chemical Properties
   Color and Form:       white xtl
   Molecular Weight:       710.1
   Melting Point:       166-170°
   Boiling Point:       240°Cdec(subl.100°/.2mm)
   Vapor Pressure:       no data
   Specific Gravity:       no data
   Odor:       none
   Solubility in Water:       insoluble

SECTION 10: Stability and Reactivity
   Stability:       air and moisture stable
   Hazardous Polymerization:       no hazardous polymerization
   Conditions to Avoid:       none
   Incompatibility:       halogens and oxidizing agents
   Decomposition Products:       carbon monoxide, carbon dioxide, yttrium oxide, fluorinated organics and organic fumes.

SECTION 11: Toxicological Information
   RTECS Data:       No information available in the RTECS files.
   Carcinogenic Effects:       No data available
   Mutagenic Effects:       No data available
   Tetratogenic Effects:       No data available

SECTION 12: Ecological Information
Ecological Information: No information available.

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
   Shipping Name (CFR):       Non-hazardous
   Hazard Class (CFR):       NA
   Additional Hazard Class (CFR):       NA
   Packaging Group (CFR):       NA
   UN ID Number (CFR):       NA
   Shipping Name (IATA):       Non-hazardous
   Hazard Class (IATA):       NA
   Additional Hazard Class (IATA):       NA
   Packaging Group (IATA):       NA
   UN ID Number (IATA):       NA

SECTION 15: Regulatory Information
   TSCA:       Not listed in the TSCA inventory
   SARA (Title 313):       Title compound not listed
   Second Ingredient:       none

SECTION 16 - ADDITIONAL INFORMATION
N/A