20440-95-3 (4,4'-二甲基三苯胺,4,4'-Dimethyltriphenylamine)

CAS号:
20440-95-3
中文名称:
4,4'-二甲基三苯胺
英文名称:
4,4'-Dimethyltriphenylamine
安全信息:
分子式:
C20H19N
分子量:
273.371565103531

4,4'-二甲基三苯胺(20440-95-3)名称与标识符

名称

中文别名:
4,4'-二甲基三苯胺;4,4'-Dimethyltriphenylamine 4,4'-二甲基三苯胺;4,4''-二甲基三苯胺;4,4-二甲基三苯胺;4,4'-二甲基三苯胺(DMTPA);4,4'-二甲基三苯胺,4,4'-Dimethyltriphenylamine;4,4鈥?-Dimethyl Triphenylamine;4,4鈥�-二甲基三苯胺;N,N-二(4-甲基苯基)苯胺;4,4’-二甲基三苯胺;4,4'-二甲基三苯胺 (DMTPA);
英文别名:
4,4'-Dimethyltriphenylamine;N-Phenyl di-p-tolylamine;4,4'-Dimethyltriphenylamine (DMTPA);4,4\'-Dimethyltriphenylamine;4,4-Dimethyltriphenylamine;4-methyl-N-(4-methylphenyl)-N-phenylaniline;4,4’-Dimethyltriphenylamine;4,4′-Dimethyltriphenylamine;Bis(4-Methylphenyl)Phenylamine;N,N-Di-p-tolylaniline;Phenyl(di-p-tolyl)amine;4,4-Dimethyltriphenylamine;;4,4'-Dimethyl Triphenylamine;Benzenamine, 4-methyl-N-(4-methylphenyl)-N-phenyl-;YWKKLBATUCJUHI-UHFFFAOYSA-N;di(p-tolyl)phenylamine;Phenyl-di-p-tolylamine;PubChem13772;Phenylbis(p-tolyl)amine;Phenyl;4,4 inverted exclamation mark -Dimethyltriphenylamine;CS-W012345;J37MWM8NNF;4,4`-Dimethyltriphenylamine;EINECS 243-822-7;N-Phenyl-N-(p-tolyl)-p-toluidine;DTXSID5066611;AC-29838;SCHEMBL57176;n,n-di(4-methylphenyl)phenylamine;AKOS015889688;20440-95-3;4-Methyl-N-phenyl-N-(p-tolyl)aniline;N-Phenyl-di-p-tolylamine;4-Methyl-N-(4-methylphenyl)-N-phenylbenzenamine;n,n-bis(4-methylphenyl)aniline;4-Methyl-N-phenyl-N-p-tolylaniline;NS00026627;MFCD00145004;SY005744;W-107621;GS-3442;FT-0616958;4-methyl-n-(4-methylphenyl)-n-phenyl-benzenamin;

标识符

MDL:
MFCD00145004
InChIKey:
YWKKLBATUCJUHI-UHFFFAOYSA-N
Inchi:
1S/C20H19N/c1-16-8-12-19(13-9-16)21(18-6-4-3-5-7-18)20-14-10-17(2)11-15-20/h3-15H,1-2H3
SMILES:
N(C1C=CC=CC=1)(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1

4,4'-二甲基三苯胺(20440-95-3)物化性质

实验特性

  • LogP : 5.77320
  • PSA : 3.24000
  • 折射率 : 1.627
  • 沸点 : 417.5±34.0 °C at 760 mmHg
  • 熔点 : 108.0 to 111.0 deg-C
  • 闪点 : 183.5℃
  • 颜色与性状 : 未确定 2. 密度(g/mL,25/4℃)
  • 密度 : 1.0790

计算特性

  • 精确分子量 : 273.15200
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 3
  • 同位素质量 : 273.152
  • 重原子数量 : 21
  • 复杂度 : 269
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 6.5
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 3.2

4,4'-二甲基三苯胺(20440-95-3)国际标准相关数据

EINECS:
243-822-7

4,4'-二甲基三苯胺(20440-95-3)海关数据

海关编码:
2921440000
海关数据:

中国海关编码:

2921440000

概述:

2921440000. 二苯胺及其衍生物以及它们的盐. 增值税率:17.0%. 退税率:17.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2921440000. diphenylamine and its derivatives; salts thereof. VAT:17.0%. Tax rebate rate:17.0%. . MFN tariff:6.5%. General tariff:30.0%

4,4'-二甲基三苯胺(20440-95-3)谱图信息

1H NMR300 MHzDMSO
1H NMR
13C NMR
13C NMR

4,4'-二甲基三苯胺(20440-95-3)相关文献

4,4'-二甲基三苯胺(20440-95-3)参考资料

Reaxys RN:
2846843
PubChem CID:

4,4'-二甲基三苯胺(20440-95-3) MSDS

基础信息

Name:N-Phenyl Di-P-Tolylamine 97% (GC) Material Safety Data Sheet
Synonym:
CAS:20440-95-3
Section 1 - Chemical Product ? MSDS Name:N-Phenyl Di-P-Tolylamine 97% (GC) Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
20440-95-3N-Phenyl Di-P-Tolylamine97243-822-7
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 20440-95-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 112 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density:
Molecular Formula: C20H19N
Molecular Weight: 273.38

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 20440-95-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-Phenyl Di-P-Tolylamine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 20440-95-3: No information available.
Canada
CAS# 20440-95-3 is listed on Canada's NDSL List.
CAS# 20440-95-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 20440-95-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A