22042-59-7 (杀螟丹,Cartap Hydrochloride Standard)

快速询单

结构式：

杀螟丹MOL文件

CAS号：

22042-59-7

中文名称：

杀螟丹

英文名称：

Cartap Hydrochloride Standard

分子式：

C₇H₁₆ClN₃O₂S₂

分子量：

273.803837776184

杀螟丹(22042-59-7)名称与标识符

名称

中文别名：

杀螟丹;1,3-二(氨基甲酰硫)-2-二甲基氨基丙烷;S,S'-(2-二甲基氨基三亚甲基)双(硫代氨基甲酸酯);WAKO033-22431杀螟丹标准品;杀螟丹标准品;杀螟丹盐酸盐标准品;

英文别名：

Cartap;S,S'-(2-Dimethylaminotrimethylene)bis(thiocarbamate);Cartap hydrochloride;Cartap Hydrochloride Standard;Propane, 1,3-bis(carbamoylthio)-2-(N,N-dimethylamino)-, monohydrochloride;2-(Dimethylamino)-1,3-propanedithiol dicarbamate hydrochloride;1,3-Propanedithiol, 2-(dimethylamino)-, dicarbamate (ester), monohydrochloride;Cartap hydrochloride, PESTANAL(R), analytical standard;cartap (hydrochloride);S,S'-(2-(Dimethylamino)-1,3-propanediyl)dicarbamothioate hydrochloride;HY-W040028;22042-59-7;DTXSID9058315;IWO0R06728;MSHXTAQSSIEBQS-UHFFFAOYSA-N;CHEMBL2270409;S,S'-(2-(Dimethylamino)trimethylene)bis(thiocarbamate) monohydrochloride;Vegetox;Kartap;S,S'-2-(dimethylamino)propane-1,3-diyl dicarbamothioate hydrochloride;15263-52-2;S-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate hydrochloride;Padan 4 G;Neristoxin dicarbamate manohydrochloride;CARTAP HYDROCHLORIDE [HSDB];EINECS 239-309-2;Carbamothioic acid, S,S'-(2-(dimethylamino)-1,3-propanediyl) ester, monohydrochloride;AMY40941;S,S'-(2-(Dimethylamino)trimethylene) bis(thiocarbamate) hydrochloride;NTD 2;1,3-Bis(carbamoylthio)-2-(N,N-dimethylamino)propane hydrochloride;CS-W020768;J-008941;S-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydrochloride;Padan;UNII-IWO0R06728;SCHEMBL122297;Kartap [Polish];1,3-Bis(carbamoylthio)-2-(N,N-dimethylamino)propane monohydrochloride;HSDB 6583;Thiocarbamic acid-S,S-(2-(dimethylamino)trimethylene) ester monohydrochloride;[1,3-bis(carbamoylsulfanyl)propan-2-yl]dimethylamine hydrochloride;Cartap hydrochloride [ISO];A809337;FT-0603063;2-Dimethylamino-1,3-bis(carbamoylthio)propane monohydrochloride;1,3-Dicarbamoylthio-2-(N,N-dimethylamino)propane monohydrochloride;NS00084834;CARTAPHYDROCHLORIDE;AKOS015897267;S,S'-(2-DIMETHYLAMINOTRIMETHYLENE) BIS(THIOCARBAMATE) HYDROCHLORIDE;1,3-Di(carbamoylthio)-2-(dimethylamino)propane hydrochloride;Patap;Suntap;AI3-27573;Cartap HCl;S,S'(2(Dimethylamino)1,3propanediyl)dicarbamothioate hydrochloride;Cartap monohydrochloride;Dihydronereistoxin dicarbamate;S,S'(2(Dimethylamino)trimethylene) bis(thiocarbamate) hydrochloride;1ST20378;Carbamothioic acid, S,S'(2(dimethylamino)1,3propanediyl) ester, hydrochloride;1,3Di(carbamoylthio)2(dimethylamino)propane hydrochloride;1,3Bis(carbamoylthio)2(N,Ndimethylamino)propane hydrochloride;Caldan;DTXCID4032037;DB-043155;

标识符

InChIKey：

MSHXTAQSSIEBQS-UHFFFAOYSA-N

Inchi：

1S/C7H15N3O2S2.ClH/c1-10(2)5(3-13-6(8)11)4-14-7(9)12;/h5H,3-4H2,1-2H3,(H2,8,11)(H2,9,12);1H

SMILES：

Cl.S(C(N)=O)CC(CSC(N)=O)N(C)C

杀螟丹(22042-59-7)物化性质

实验特性

LogP : 1.94100
PSA : 140.02000
沸点 : 407.2 °C at 760 mmHg
熔点 : 407.2°C at 760mmHg
闪点 : 200.1°C
颜色与性状 : No data avaiable
密度 : 1.42 (20 C)

计算特性

精确分子量 : 237.06100
氢键供体数量 : 3
氢键受体数量 : 5
可旋转化学键数量 : 7
同位素质量 : 273.037
重原子数量 : 15
复杂度 : 193
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 2
拓扑分子极性表面积 : 140A^2

杀螟丹(22042-59-7)安全信息

RTECS号： FD1225000
安全说明： H302
风险术语： R22
危险品标志： Xn
危害声明：H302 H313 H314
警示性声明：P264+P280+P305+P351+P338+P337+P313
储存条件： 4°C条件下存储,-4摄氏度存储更佳
危险类别码： 22
信号词： Danger

杀螟丹(22042-59-7)海关数据

海关编码：

2930200011

海关数据：

中国海关编码：

2930200011

概述：

2930200011 禾草丹、杀螟丹。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

申报要素：

品名, 成分含量, 用途

监管条件：

S.进出口农药登记证明

Summary：

2930200011 s,s'-(2-(dimethylamino)propane-1,3-diyl) dicarbamothioate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

杀螟丹(22042-59-7)生产方法和用途

用途：

用于防治蔬菜、稻、麦、果树等作物的虫害

生产方法：

由氯丙烯经二甲胺胺化、氯气氯化、硫代硫酸钠及氰化钠硫氰化而得。胺化反应将40%二甲胺和40%碱液于0～15℃时约0.5h内滴入到氯丙烯中，滴毕于45℃保温反应2h，静置分层得N，N-二甲基丙烯胺。原料配比为：氯丙烯：二甲胺：氢氧化钠=1:1.2:1.3(mol)。收率82%。氯化反应将干燥的氯化氢气体于0～10℃通入到丙烯胺、氯仿溶液中。然后于20℃通氯气，静置，分离氯仿层，再将固体氯化物再水充分溶解，静置0.5h，分去残留氯仿。氯化产物1-N，N-二甲基-2，3-二氯丙胺盐酸盐收率91.32%。丙烯胺与氯化氢、氯气的配比为1:1:(1～1.05)，氯仿用量为每千摩投250L。硫氰化反应先将碱液滴入氯化物水溶液中，再将硫代硫酸钠滴入。然后升温至60℃于60～65℃保温反应4h。将磺化物抽入氰化釜中，于13～15℃将氰化钠溶液滴入其中，滴毕保温反应1h,离心分离，低温洗盐，离心分离，得2-N，N-二甲基-1，3-二硫氰基丙烷。原料配比为氯化物：硫代硫酸钠：氰化钠=1:2.08:2.3。氢氧化钠用量为氯化物水溶液总酸度（mg/mL)×投料量（L）×0.972。磺化温度60℃，时间4h；氰化温度（13±2）℃，时间1h。或将1-N，N-二甲基-2，3-二氯丙胺盐酸先用碱中和成游离碱，再与硫氰酸盐在甲醇中硫氰化反应制得。醇解反应将硫氰酸酯与甲醇混合后，降温至0℃，通入干燥氯化氢，保持温度0～10℃，通毕升温至50℃，保温反应3h，降温至0℃，再保温2h，离心分离，产品去干燥，滤液待回收，收率96%。醇解原料配比为硫化物：HC1=1:10，甲醇用量为450L/1000mol硫代物。

杀螟丹(22042-59-7)推荐厂家更多厂家(21)

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湖北鑫红利化工有限公司	15172537016 027-59503710	祝雨薇	1018283355	询单
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杀螟丹(22042-59-7)相关文献

1. Ligand exchange reactions on citrate-gold nanoparticles for a parallel colorimetric assay of six pesticides
Kirankumar Rana,Jigna R. Bhamore,Jigneshkumar V. Rohit,Tae-Jung Park,Suresh Kumar Kailasa New J. Chem. 2018 42 9080
2. The ABCs of pesticide toxicology: amounts, biology, and chemistry
John E. Casida,Robert J. Bryant Toxicol. Res. 2017 6 755
3. The crystal and molecular structure of 1,3-bis(thiocarbamoyl)-2-NN-dimethylaminopropane hydrochloride (Cartap)
Clair J. Cheer,Francis J. Pickles J. Chem. Soc. Perkin Trans. 2 1980 1805

杀螟丹(22042-59-7)参考资料

Reaxys RN：

PubChem CID：

30913

杀螟丹(22042-59-7) MSDS

基础信息

Version 1.0
Regulation (EC) No 1907/2006

1 - Product and Company Information

Product Name CARTAP, 500MG, NEAT

2 - Hazards Identification

SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
Harmful if swallowed.

3 - Composition/Information on Ingredients

    Product Name        CAS #        EC no        Annex I
    Index Number
    CARTAP        22042-59-7 None        None
    Formula        C7H15N3O2S2
    Molecular Weight 273,8300 AMU
    Synonyms        S,S'-(2-Dimethylaminotrimethylene)bis(thiocarbama
    te)

4 - First Aid Measures

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER SKIN CONTACT
    In case of skin contact, flush with copious amounts of water for
    at least 15 minutes. Remove contaminated clothing and shoes.
    Call a physician.
    AFTER EYE CONTACT
    In case of contact with eyes, flush with copious amounts of
    water for at least 15 minutes. Assure adequate flushing by
    separating the eyelids with fingers. Call a physician.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician.

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5 - Fire Fighting Measures

    EXTINGUISHING MEDIA
    Suitable: Water spray. Carbon dioxide, dry chemical powder, or
    appropriate foam.
    SPECIAL RISKS
    Specific Hazard(s): Emits toxic fumes under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

6 - Accidental Release Measures

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Sweep up, place in a bag and hold for waste disposal. Avoid
    raising dust. Ventilate area and wash spill site after material
    pickup is complete.

7 - Handling and Storage

    HANDLING
    Directions for Safe Handling: Do not breathe dust. Avoid contact
    with eyes, skin, and clothing. Avoid prolonged or repeated
    exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed.
    SPECIAL REQUIREMENTS: Hygroscopic. Handle and store under
    nitrogen.

8 - Exposure Controls / Personal Protection

    ENGINEERING CONTROLS
    Mechanical exhaust required. Safety shower and eye bath.
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Respiratory Protection: Use respirators and components tested and
    approved under appropriate government standards such as NIOSH (US)
    or CEN (EU). Where risk assessment shows air-purifying respirators
    are appropriate use a full-face particle respirator type N99 (US)
    or type P2 (EN 143) respirator cartridges as a backup to
    engineering controls. If the respirator is the sole means of
    protection, use a full-face supplied air respirator.
    Hand Protection: Compatible chemical-resistant gloves.
    Eye Protection: Chemical safety goggles.

9 - Physical and Chemical Properties
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    Appearance        Physical State: Solid
    Color: White
    Form: Crystalline
    Odor: Odorless
    Property        Value        At Temperature or Pressure
    pH N/A
    BP/BP Range        N/A
    MP/MP Range        179,000. - 181,000 °
    C.
    Flash Point        N/A
    Flammability        N/A
    Autoignition Temp        N/A
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A
    Vapor Pressure        N/A
    Partition Coefficient N/A
    Viscosity        N/A
    Vapor Density        N/A
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A
    Bulk Density        N/A
    Decomposition Temp.        N/A
    Solvent Content        N/A
    Water Content        N/A
    Surface Tension        N/A
    Conductivity        N/A
    Miscellaneous Data        N/A
    Solubility        N/A

10 - Stability and Reactivity

    STABILITY
    Stable: Stable.
    Materials to Avoid: Strong oxidizing agents.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, carbon dioxide,
    and nitrogen oxides, Sulfur oxides, Hydrogen chloride gas.
    HAZARDOUS POLYMERIZATION
    Hazardous Polymerization: Will not occur

11 - Toxicological Information

    ACUTE TOXICITY
    LD50
    Oral
    Rat
    250,000000 mg/kg
    LD50
    Oral
    Mouse
    165,000000 mg/kg
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    LD50
    Skin
    Mouse
    > 1000,000000 mg/kg
    LD50
    Intravenous
    Mouse
    59 MG/KG
    Remarks: Behavioral:Convulsions or effect on seizure threshold.
    Lungs, Thorax, or Respiration:Respiratory depression.
    LD50
    Oral
    Mammal
    390,000000 mg/kg
    SIGNS AND SYMPTOMS OF EXPOSURE
    To the best of our knowledge, the chemical, physical, and
    toxicological properties have not been thoroughly investigated.
    ROUTE OF EXPOSURE
    Skin Contact: May cause skin irritation.
    Skin Absorption: May be harmful if absorbed through the skin.
    Eye Contact: May cause eye irritation.
    Inhalation: Material may be irritating to mucous membranes and
    upper respiratory tract. May be harmful if inhaled.
    Ingestion: Harmful if swallowed.
    CHRONIC EXPOSURE - TERATOGEN
    Species: Rat
    Dose: 700 MG/KG
    Route of Application: Oral
    Exposure Time: (9-15D PREG)
    Result: Specific Developmental Abnormalities: Musculoskeletal
    system.
    Species: Hamster
    Dose: 300 MG/KG
    Route of Application: Oral
    Exposure Time: (8-13D PREG)
    Result: Specific Developmental Abnormalities: Musculoskeletal
    system.

12 - Ecological Information

No data available.

13 - Disposal Considerations

    SUBSTANCE DISPOSAL
    Contact a licensed professional waste disposal service to dispose
    of this material. Dissolve or mix the material with a combustible
    solvent and burn in a chemical incinerator equipped with an
    afterburner and scrubber. Observe all federal, state, and local
    environmental regulations.

14 - Transport Information

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    RID/ADR
    Non-hazardous for road transport.
    IMDG
    Non-hazardous for sea transport.
    IATA
    Non-hazardous for air transport.

15 - Regulatory Information

    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: Xn
    Harmful.
    R-PHRASES: 22
    Harmful if swallowed.
    Caution: Substance not yet fully tested (EU).

16 - Other Information

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
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SECTION 16 - ADDITIONAL INFORMATION
N/A