2212-81-9 (1,3-双(叔丁基过氧异丙基)苯,1,3-Bis(tert-butylperoxyisopropyl)benzene)

CAS号:
2212-81-9
中文名称:
1,3-双(叔丁基过氧异丙基)苯
英文名称:
1,3-Bis(tert-butylperoxyisopropyl)benzene
分子式:
C20H34O4
分子量:
338.481566905975

1,3-双(叔丁基过氧异丙基)苯(2212-81-9)名称与标识符

名称

中文别名:
1,3-双(叔丁基过氧异丙基)苯;1,3-双丁基过氧异丙基苯;二(叔丁基过氧化异丙基)苯;二叔丁基过氧化异丙基苯;无味交联剂BIPB;双叔丁基过氧化二异丙基苯;交联剂BIPB;无味DCP;无味交联剂;
英文别名:
1,3-Bis(tert-butylperoxyisopropyl)benzene;1,3-Bis(2-tert-butylperoxy-2-propyl)benzene;m-Bis[2-(tert-butylperoxy)-2-propyl]benzene;C20H34O4;DI(TERT-BUTYLPEROXYISOPROPYL)BENZENE;Di(tert-butylperoxyisopropyl)benzene, Mixture of isoMers;Bis(tert-butyldioxyisopropyl)benzene;[1,3-phenylenebis(1-methylethylidene)]bis[tert-butyl] peroxide;1,3-Bis-(2-tert-butylperoxiisopropyl)benzol;1,3-bis(t-butylperoxyisopropyl)benzene;14s;BIBP;LINKWELL BIPB;Luperox 802;m-bis-(2-tert-Butylperoxy-2-propyl)benzene;Perbutyl PT;Perhexa F 40;Perkadox?14S;PEROXAN BIB;Peroximon F;PERKADOX 14/40;1,3-bis(2-tert-butylperoxypropan-2-yl)benzene;DTXSID50862872;Peroxide,1,1'-[1,3-phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl);m-Bis(2-tert-butylperoxyisopropyl)benzene;UBRWPVTUQDJKCC-UHFFFAOYSA-N;(1,3-Phenylenebis(1-methylethylidene))bis(tert-butyl) peroxide;SCHEMBL44643;1,3-Di-tert-butylperoxydiisopropylbenzene;Peroxide, 1,1'-[1,3-phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl);1,3-Bis[alpha-(tert-butyldioxy)isopropyl]benzene;5C532BF77V;alpha,alpha'-Bis(tert-butylperoxy)-1,3-diisopropylbenzene;EC 218-664-7;1,1'-[1,3-Phenylenebis(1-methylethylidene)]bis[2-(1,1-dimethylethyl) peroxide];2212-81-9;EINECS 218-664-7;1,3-Bis(2-t-butylperoxy-2-propyl)benzene;(1,3-Phenylenebis(1-methylethylidene)bis(tert-butyl) peroxide;1,3-Bis(1-tert-butyldioxy-1-methylethyl)benzene;NS00006213;Peroxide, (m-phenylenediisopropylidene)bis[tert-butyl;1,4-Bis(tert-butylperoxydiisopropyl)benzene;218-664-7;

标识符

MDL:
MFCD01940629
InChIKey:
UBRWPVTUQDJKCC-UHFFFAOYSA-N
Inchi:
1S/C20H34O4/c1-17(2,3)21-23-19(7,8)15-12-11-13-16(14-15)20(9,10)24-22-18(4,5)6/h11-14H,1-10H3
SMILES:
O(C(C)(C)C1C=CC=C(C=1)C(C)(C)OOC(C)(C)C)OC(C)(C)C

1,3-双(叔丁基过氧异丙基)苯(2212-81-9)物化性质

实验特性

  • LogP : 5.38700
  • PSA : 36.92000
  • 折射率 : 1.6000 (estimate)
  • 沸点 : 360 ºC
  • 熔点 : 43-48℃
  • 闪点 : 113 ºC
  • 颜色与性状 : 白色或黄色有微弱气味的薄片
  • 溶解性 : 不溶于水
  • 密度 : 0.974

计算特性

  • 精确分子量 : 338.24600
  • 氢键供体数量 : 0
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 8
  • 同位素质量 : 338.24570956g/mol
  • 重原子数量 : 24
  • 复杂度 : 351
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 4.5
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 36.9

1,3-双(叔丁基过氧异丙基)苯(2212-81-9)安全信息

1,3-双(叔丁基过氧异丙基)苯(2212-81-9)国际标准相关数据

EINECS:
218-664-7

1,3-双(叔丁基过氧异丙基)苯(2212-81-9)海关数据

海关编码:
2909600000
海关数据:

中国海关编码:

2909600000

概述:

2909600000 过氧化醇、过氧化醚、过氧化酮及其卤化、磺化、硝化、亚硝化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909600000 alcohol peroxides, ether peroxides, ketone peroxides and their halogenated, sulphonated, nitrated or nitrosated derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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1,3-双(叔丁基过氧异丙基)苯(2212-81-9) MSDS

基础信息

Name:Di(tert-butylperoxyisopropyl)benzene Material Safety Data Sheet
Synonym:
CAS:2212-81-9
Section 1 - Chemical Product ? MSDS Name:Di(tert-butylperoxyisopropyl)benzene Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
2212-81-9Di(tert-butylperoxyisopropyl)benzene218-664-7
Hazard Symbols: XI O
Risk Phrases: 36 7

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes. May cause fire.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Non-irritating to the skin. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid mechanical shock and friction.
Storage:
Do not store near combustible materials. Store in a tightly closed container. Store in a dry area. Keep refrigerated. (Store below 4C/39F.) Keep away from reducing agents.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 2212-81-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: white
Odor: faint odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 44 - 48 deg C
Autoignition Temperature: > 380 deg C (> 716.00 deg F)
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C20H34O4
Molecular Weight: 338.49

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by direct contact with incompatible substances or by thermal decomposition at and above the SADT (see Section 16).
Conditions to Avoid:
Incompatible materials, ignition sources, combustible materials.
Incompatibilities with Other Materials:
Reducing agents, acids, bases, rust, heavy metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acetone, methane.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 2212-81-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Di(tert-butylperoxyisopropyl)benzene - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
? Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI O
Risk Phrases:
R 36 Irritating to eyes.
R 7 May cause fire.
Safety Phrases:
S 3/7 Keep container tightly closed in a cool,
well-ventilated place.
S 14A Keep away from acids, reducing agents and
polymerisation catalysts.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 2212-81-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2212-81-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2212-81-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A