2362-12-1 (4-溴-2-甲基苯酚,4-Bromo-2-methylphenol)

快速询单

结构式：

4-溴-2-甲基苯酚MOL文件

CAS号：

2362-12-1

中文名称：

4-溴-2-甲基苯酚

英文名称：

4-Bromo-2-methylphenol

安全信息：

分子式：

C₇H₇BrO

分子量：

187.033881425858

4-溴-2-甲基苯酚(2362-12-1)名称与标识符

名称

中文别名：

4-溴-2-甲基苯酚;4-溴邻甲基苯酚;2-甲基-4-溴苯酚;2-三氟甲基苯酚;4-Bromo-o-cresol 4-溴邻甲基苯酚;4-溴-2-甲基苯酚,4-Bromo-2-methylphenol;4-溴-o-甲酚;4-溴邻甲酚;

英文别名：

4-Bromo-2-methylphenol;4-Bromo-o-cresol;2-hydroxy-5-bromotoluene;2-methyl-4-bromophenol;4-Br-2-MeC6H3OH;4-Br-2-me-phenol;4-bromo-2-methyl-phenol;methyl-p-Bromophenol;o-CRESOL,4-BROMO;J-514678;BRN 2041491;MFCD00055435;AKOS000319641;FT-0634218;p-bromocresol;CS-W016867;AN-329/40925146;Z57203793;AM20060305;SCHEMBL49677;4-bromo-cresol;CHEMBL224022;4-Bromo-2-methylphenol, 97%;MWJ;o-CRESOL, 4-BROMO-;B3677;AC-23052;DTXSID80178291;PS-8465;Phenol, 4-bromo-2-methyl-;J-015168;BCP27415;4-06-00-02006 (Beilstein Handbook Reference);2362-12-1;EN300-18140;SY016814;DB-000369;DTXCID10100782;STK082965;627-649-8;

标识符

MDL：

MFCD00055435

InChIKey：

IWJGMJHAIUBWKT-UHFFFAOYSA-N

Inchi：

1S/C7H7BrO/c1-5-4-6(8)2-3-7(5)9/h2-4,9H,1H3

SMILES：

BrC1C=CC(=C(C)C=1)O

4-溴-2-甲基苯酚(2362-12-1)物化性质

实验特性

LogP : 2.46310
PSA : 20.23000
折射率 : 1.5772 (estimate)
水溶性 : Slightly soluble in water.
沸点 : 88°C/1.5mmHg(lit.)
熔点 : 63-67 °C
闪点 : 98.7℃
密度 : 1.3839 (rough estimate)

计算特性

精确分子量 : 185.96800
氢键供体数量 : 1
氢键受体数量 : 1
可旋转化学键数量 : 0
同位素质量 : 185.968027
重原子数量 : 9
复杂度 : 94.9
同位素原子数量 : 0
确定原子立构中心数量 : 0
不确定原子立构中心数量 : 0
确定化学键立构中心数量 : 0
不确定化学键立构中心数量 : 0
共价键单元数量 : 1
疏水参数计算参考值（XlogP） : 2
拓扑分子极性表面积 : 20.2

4-溴-2-甲基苯酚(2362-12-1)安全信息

符号： GHS07
RTECS号： GO6868000
WGK Germany： 3
安全说明： S26; S36/37/39
风险术语： R22
危险品标志： Xn
危险品运输编号： NONH for all modes of transport
危害声明：H302
警示性声明：P264-P270-P280-P301+P312+P330-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501
提示语：警告
危险类别码： 22
信号词： Warning
HazardClass： IRRITANT, IRRITANT-HARMFUL

4-溴-2-甲基苯酚(2362-12-1)海关数据

海关编码：

2908199090

海关数据：

中国海关编码：

2908199090

概述：

HS:2908199090 其他酚及酚醇的仅含卤素取代基的衍生物及其盐增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

4-溴-2-甲基苯酚(2362-12-1)推荐厂家更多厂家(31)

公司名称	手机号/电话	联系人	QQ	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
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郑州阿尔法化工有限公司	15324716602 0371-55013243	刘经理	2853979810	询单
南通众合化工新材料有限公司	18762756250 0513-55074056	胡经理	2369399482	询单
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湖北云镁科技有限公司	18327059871 027-59206672	方经理	235010015	询单
上海腾准生物科技有限公司	19821570922 021-34053661	张经理	3003871136	询单
上海超岚化工科技中心	13301690235	linda	3027278462	询单
赫澎（上海）生物科技有限公司	13122891558 186-16545970	张硕	3418426269	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单

4-溴-2-甲基苯酚(2362-12-1)上下游

4-羟基-3-甲基-1-氰基苯 5-溴-7-甲基苯并呋喃 4-溴-2-甲基-6-硝基苯酚 4-苄氧基-3-甲基苯硼酸 2-Amino-4-bromo-6-methylphenol 3-羟基-4-甲基苯腈 4-羟基-3-甲基-[1,1-联苯]-4-甲腈 5-溴-2-(二氟甲氧基)甲苯 4-溴-2-甲基苯胺 2-甲酚

4-溴-2-甲基苯酚(2362-12-1)相关文献

1. Organic chemistry
J. Chem. Soc. Abstr. 1913 104 i813
2. Reactions of alkyl-lithium compounds with aryl halides
Penelope A. Huddle,Guido W. Perold J. Chem. Soc. Perkin Trans. 1 1980 2617
3. QSAR for the cytotoxicity of 2-alkyl or 2,6-dialkyl, 4-X-phenols: the nature of the radical reaction
Cynthia D. Selassie,Rajeshwar P. Verma,Sanjay Kapur,Alan J. Shusterman,Corwin Hansch J. Chem. Soc. Perkin Trans. 2 2002 1112
4. CCLXXIII.—Nitrosation of phenols. Part III. Nitrosation of 4-halogeno-o- and -m-cresols and oximation of the 4-halogeno-2 : 5-toluquinones
Herbert Henry Hodgson,Francis Harry Moore J. Chem. Soc. 1926 129 2036
5. 258. Phthalaldehydes and related compounds. Part II. Synthesis of isogladiolic acid
J. J. Brown,G. T. Newbold J. Chem. Soc. 1953 1285
6. 200. Acid-catalysed rearrangements of alkyl aryl ethers. Part IV. Rearrangement of alkyl tolyl ethers by aluminium chloride
M. J. S. Dewar,N. A. Puttnam J. Chem. Soc. 1960 959
7. Synthesis and liquid-crystalline properties of novel laterally connected twins: the influence of the connecting topology and the length of the rigid core
Jens Andersen,Carsten Tschierske,Siegmar Diele,Dirk Lose J. Mater. Chem. 1996 6 1297
8. Participation of o-carboxylate groups in aromatic nucleophilic substitution
R. Muthukrishnan,R. Kannan,S. Swaminathan J. Chem. Soc. Perkin Trans. 1 1973 2949
9. 138. The search for chemotherapeutic amidines. Part X. Substituted 4 : 4′-diamidino-αω-diphenoxyalkanes and -diphenyl ethers
S. S. Berg,G. Newbery J. Chem. Soc. 1949 642

4-溴-2-甲基苯酚(2362-12-1)参考资料

Reaxys RN：

2041491

PubChem CID：

24885618

4-溴-2-甲基苯酚(2362-12-1) MSDS

基础信息

4-Bromo-o-cresol Revision number: 1
SAFETY DATA SHEET

Section 1. BASE INFORMATION
Product name: 4-Bromo-o-cresol

Revision number: 1

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified
  HEALTH HAZARDS        Not classified
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements
    None
  Pictograms or hazard symbols
  Signal word        No signal word
    None
  Hazard statement
  Precautionary statements        None

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance
  Component(s):        4-Bromo-o-cresol
  Percent:        ....
  CAS Number:        2362-12-1
  Synonyms:        4-Bromo-2-methylphenol
  Chemical Formula:        C7H7BrO

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.
  media:
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  4-Bromo-o-cresol

Section 5. FIRE-FIGHTING MEASURES
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Corect spilled material into an airtight container. Adhered or collected material
  containment and cleaning should be promptly disposed of, in accordance with appropriate laws and regulations.
  up:

Section 7. HANDLING AND STORAGE
  Handling
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.
    Store away from incompatible materials such as oxidizing agents.
    Law is followed.
  Packaging material:

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Odor:        No data available
  pH: No data available
  Melting point/freezing point:No data available
  Boiling Point/Range:        No data available
  Flash Point:        No data available
  Explosive limits
  Lower:        No data available
  Upper:        No data available
  Density:        No data available
  Solubility:        No data available

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.
    No special reactivity has been reported.
  Reactivity:
  Incompartible materials: oxidizing agents
  Hazardous Decomposition carbon monoxide, carbon dioxide etc.
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available
  Skin corrosion/irritation: No data available
  Serious eye        No data available
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available
  4-Bromo-o-cresol

Section 11. TOXICOLOGICAL INFORMATION
NTP = No data available
Reproductive toxicity: No data available

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available
  Crustacea:        No data available
  Algae:        No data available
  Persistence / degradability: No data available
  Bioaccumulative        No data available
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available
  Soil adsorption (Koc):        No data available
  Henry's Law        No data available
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local
regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
UN-No: Not Listed

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.

SECTION 16 - ADDITIONAL INFORMATION
N/A