2386-64-3 (乙基氯化镁,Ethylmagnesium Chloride (2M, Et2O))

    Version 1.4
    Regulation (EC) No 1907/2006

---

    1 - Product and Company Information

---

    Product Name        ETHYLMAGNESIUM CHLORIDE SOLUTION,    
    APPROX. 2.8 M IN TETRAHYDROFURAN

---

    2 - Hazards Identification

---

    SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT
    Highly flammable. Reacts violently with water, liberating
    extremely flammable gases. Causes burns.

---

    3 - Composition/Information on Ingredients

---

    Product Name        CAS #        EC no        Annex I    
    Index Number
    ETHYLMAGNESIUM CHLORIDE SOLUTION, None        None        None    
    ~2.8 M IN TETRAHYDROFURAN
    Ingredient Name        Percent        CAS #        EC no        Annex I    
    Index Number
    ETHYLMAGNESIUM CHLORIDE >= 20        2386-64-3        219-206-9 None    
    <=>
    TETRAHYDROFURAN        >= 75        109-99-9 203-726-8 603-025-00-0    
    (Inhibitor free)        <=>
    Symbols: F-Xi
    R-Phrases: 11-19-36/37
    Highly flammable. May form explosive peroxides. Irritating to eyes
    and respiratory system.
    Formula        C2H5ClMg    
    Molecular Weight 88,8300 AMU

---

    4 - First Aid Measures

---

    AFTER INHALATION
    If inhaled, remove to fresh air. If not breathing give
    artificial respiration. If breathing is difficult, give oxygen.
    AFTER EYE CONTACT
    FLUKA        www.molbase.com    
    Assure adequate flushing of the eyes by separating the eyelids
    with fingers.
    AFTER INGESTION
    If swallowed, wash out mouth with water provided person is
    conscious. Call a physician.

---

    5 - Fire Fighting Measures

---

    CONDITIONS OF FLAMMABILITY
    Reacts with water to liberate flammable and/or explosive gas.
    EXTINGUISHING MEDIA
    Suitable: Dry chemical powder.
    Unsuitable: Do not use water.
    SPECIAL RISKS
    Specific Hazard(s): Vapor may travel considerable distance to
    source of ignition and flash back. Emits toxic fumes under fire
    conditions.
    Explosion Hazards: Vapor may travel considerable distance to
    source of ignition and flash back. Container explosion may occur
    under fire conditions.
    SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS
    Wear self-contained breathing apparatus and protective clothing
    to prevent contact with skin and eyes.

---

    6 - Accidental Release Measures

---

    PERSONAL PRECAUTION PROCEDURES TO BE FOLLOWED IN CASE OF LEAK OR SPILL
    Evacuate area. Shut off all sources of ignition.
    PROCEDURE(S) OF PERSONAL PRECAUTION(S)
    Wear self-contained breathing apparatus, rubber boots, and heavy
    rubber gloves.
    METHODS FOR CLEANING UP
    Cover with dry-lime, sand, or soda ash. Place in covered
    containers using non-sparking tools and transport outdoors.
    Ventilate area and wash spill site after material pickup is
    complete.

---

    7 - Handling and Storage

---

    HANDLING
    Directions for Safe Handling: Do not breathe vapor. Do not get
    in eyes, on skin, on clothing. Avoid prolonged or repeated
    exposure.
    STORAGE
    Conditions of Storage: Keep tightly closed. Keep away from heat,
    sparks, and open flame. Store in a cool dry place.
    Incompatible Materials: Do not allow contact with water

---

    8 - Exposure Controls / Personal Protection

---

    ENGINEERING CONTROLS
    Safety shower and eye bath. Use only in a chemical fume hood.
    FLUKA        www.molbase.com    
    GENERAL HYGIENE MEASURES
    Wash thoroughly after handling.
    PERSONAL PROTECTIVE EQUIPMENT
    Special Protective Measures: Wear appropriate government approved
    respirator, chemical-resistant gloves, safety goggles, other
    protective clothing. Faceshield (8-inch minimum).

---

    9 - Physical and Chemical Properties

---

    Appearance        Physical State: Liquid    
    Color: Dark - brown
    Property        Value        At Temperature or Pressure    
    pH N/A
    BP/BP Range        N/A    
    MP/MP Range        N/A    
    Flash Point        - 17,000 °C.        Method: closed cup    
    Flammability        N/A    
    Autoignition Temp        N/A    
    Oxidizing Properties N/A
    Explosive Properties N/A
    Explosion Limits        N/A    
    Vapor Pressure        N/A    
    SG/Density        0,9780 g/cm3    
    Partition Coefficient N/A
    Viscosity        N/A    
    Vapor Density        N/A    
    Saturated Vapor Conc. N/A
    Evaporation Rate        N/A    
    Bulk Density        N/A    
    Decomposition Temp.        N/A    
    Solvent Content        N/A    
    Water Content        N/A    
    Surface Tension        N/A    
    Conductivity        N/A    
    Miscellaneous Data        N/A    
    Solubility        N/A    

---

    10 - Stability and Reactivity

---

    STABILITY
    Reactions to Avoid: Reacts violently with:
    Materials to Avoid: Water, Acids, Alcohols.
    HAZARDOUS DECOMPOSITION PRODUCTS
    Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
    Hydrogen chloride gas.

---

    11 - Toxicological Information

---

    SIGNS AND SYMPTOMS OF EXPOSURE
    Coughing, chest pains, difficulty in breathing. Nausea,
    dizziness, and headache. Unconsciousness. Material is extremely
    destructive to tissue of the mucous membranes and upper
    respiratory tract, eyes, and skin. Inhalation may result in
    spasm, inflammation and edema of the larynxand bronchi, chemical
    pneumonitis, and pulmonary edema. Symptoms of exposure may
    include burning sensation, coughing, wheezing, laryngitis,
    FLUKA        www.molbase.com    
    shortness of breath, headache, nausea, and vomiting. Narcotic
    effect. Exposure can cause: Can cause CNS depression.
    ROUTE OF EXPOSURE
    Multiple Routes: Harmful if swallowed, inhaled, or absorbed
    through skin.
    TARGET ORGAN INFORMATION
    Central nervous system. Liver. Kidneys.

---

    12 - Ecological Information

---

    No data available.

---

    13 - Disposal Considerations

---

    SUBSTANCE DISPOSAL
    Under an inert atmosphere, cautiously add the material to dry
    butanol in an appropriate solvent. The chemical reaction may be
    vigorous and/or exothermic. Provisions must be made for the
    venting of large volumes of highly flammable hydrogen and/or
    hydrocarbon gases. Neutralize the solution with aqueous acid.
    Filter off any solid residues for disposal as hazardous waste.
    Burn the liquid portion in a chemical incinerator equipped with an
    afterburner and scrubber. Observe all federal, state, and local
    environmental regulations.

---

    14 - Transport Information

---

    RID/ADR
    UN#: 3399
    Class: 4.3
    PG: I
    Subrisk: 3
    Proper Shipping Name: Organometallic substance,
    liquid, water-reactive, flammable
    IMDG
    UN#: 3399
    Class: 4.3
    PG: I
    Subrisk: 3
    Proper Shipping Name: Organometallic substance,
    liquid, water-reactive, flammable
    Marine Pollutant: No
    Severe Marine Pollutant: No
    Technical Name: Required
    IATA
    UN#: 3399
    Class: 4.3
    PG: I
    Subrisk: 3
    Proper Shipping Name: Organometallic substance,
    liquid, water-reactive, flammable
    Inhalation Packing Group I: No
    Technical Name: Required

---

    15 - Regulatory Information

---

    FLUKA        www.molbase.com    
    CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES
    INDICATION OF DANGER: F-C
    Highly Flammable. Corrosive.
    R-PHRASES: 11-14/15-34
    Highly flammable. Reacts violently with water, liberating
    extremely flammable gases. Causes burns.
    S-PHRASES: 7/8-26-30-36/37/39-43-45
    Keep container tightly closed and dry. In case of contact with
    eyes, rinse immediately with plenty of water and seek medical
    advice. Never add water to this product. Wear suitable
    protective clothing, gloves, and eye/face protection. In case
    of fire, use special powder for metal fire. Never use water. In
    case of accident or if you feel unwell, seek medical advice
    immediately (show the label where possible).
    Caution: Substance not yet fully tested (EU).
    COUNTRY SPECIFIC INFORMATION
    Germany
    WGK: 1
    Self-Classification

---

    16 - Other Information

---

    WARRANTY
    The above information is believed to be correct but does not
    purport to be all inclusive and shall be used only as a guide. The
    information in this document is based on the present state of our
    knowledge and is applicable to the product with regard to
    appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. Inc.,
    shall not be held liable for any damage resulting from handling or
    from contact with the above product. See reverse side of invoice
    or packing slip for additional terms and conditions of sale.
    Copyright 2010 Co. License granted to make
    unlimitedpaper copies for internal use only.
    DISCLAIMER
    For R&D use only. Not for drug, household or other uses.
    FLUKA        www.molbase.com    

---

SECTION 16 - ADDITIONAL INFORMATION
N/A